A Tetranuclear, Macrocyclic 3d−4f Complex Showing Single-Molecule Magnet Behavior

[CuII 3TbIII(L Pr )(NO3)2(MeOH)(H2O)2](NO3)·3H2O is a rare example of a 3d−4f single-molecule magnet prepared using a macrocyclic ligand: at low T, it exhibits frequency-dependent alternating-current susceptibility, indicative of slow relaxation of the magnetization.

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Bibliographic Details
Published in:Inorganic chemistry 2011-05, Vol.50 (10), p.4232-4234
Main Authors: Feltham, Humphrey L. C, Clérac, Rodolphe, Powell, Annie K, Brooker, Sally
Format: Article
Language:English
Subjects:
Chemical Sciences
Inorganic chemistry
Material chemistry
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Summary:[CuII 3TbIII(L Pr )(NO3)2(MeOH)(H2O)2](NO3)·3H2O is a rare example of a 3d−4f single-molecule magnet prepared using a macrocyclic ligand: at low T, it exhibits frequency-dependent alternating-current susceptibility, indicative of slow relaxation of the magnetization.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic2003639