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Characterization of Thin MgO Films on Ag(001) by Low-Energy Electron Diffraction and Scanning Tunneling Microscopy
The evolution of the MgO(001) film morphology on Ag(001) was studied in dependence on the growth temperature (373−673 K) and grown MgO quantity (0.2−2 ML) by low-energy electron diffraction and scanning tunneling microscopy. We evidence an island growth mode of MgO for all temperatures. At 373 K, th...
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Published in: | Journal of physical chemistry. C 2011-04, Vol.115 (16), p.8034-8041 |
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container_title | Journal of physical chemistry. C |
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creator | Ouvrard, Aimeric Niebauer, Johannes Ghalgaoui, Ahmed Barth, Clemens Henry, Claude R Bourguignon, Bernard |
description | The evolution of the MgO(001) film morphology on Ag(001) was studied in dependence on the growth temperature (373−673 K) and grown MgO quantity (0.2−2 ML) by low-energy electron diffraction and scanning tunneling microscopy. We evidence an island growth mode of MgO for all temperatures. At 373 K, the MgO film exhibits a high island density, which is due to a too small surface mobility of the film compounds during the film growth. At a growth temperature of 673 K, silver hampers a perfect growth of MgO islands due to its high mobility, which leads to dendrites of MgO. The flattest and largest MgO islands are obtained at a growth temperature of around 573 K, which is a compromise guaranteeing a sufficiently high Mg or MgO mobility but also an enough low diffusion of silver. |
doi_str_mv | 10.1021/jp1095823 |
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We evidence an island growth mode of MgO for all temperatures. At 373 K, the MgO film exhibits a high island density, which is due to a too small surface mobility of the film compounds during the film growth. At a growth temperature of 673 K, silver hampers a perfect growth of MgO islands due to its high mobility, which leads to dendrites of MgO. The flattest and largest MgO islands are obtained at a growth temperature of around 573 K, which is a compromise guaranteeing a sufficiently high Mg or MgO mobility but also an enough low diffusion of silver.</description><identifier>ISSN: 1932-7447</identifier><identifier>EISSN: 1932-7455</identifier><identifier>DOI: 10.1021/jp1095823</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>C: Surfaces, Interfaces, Catalysis</subject><ispartof>Journal of physical chemistry. 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title | Characterization of Thin MgO Films on Ag(001) by Low-Energy Electron Diffraction and Scanning Tunneling Microscopy |
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