Why hybrid porous solids capture greenhouse gases?

Hybrid porous solids, with their tunable structures, their multifunctional properties and their numerous applications, are currently topical, particularly in the domain of adsorption and storage of greenhouse gases. Most of the data reported so far concern the performances of these solids in this do...

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Bibliographic Details
Published in:Chemical Society reviews 2011-02, Vol.40 (2), p.550-562
Main Authors: Férey, Gérard, Serre, Christian, Devic, Thomas, Maurin, Guillaume, Jobic, Hervé, Llewellyn, Philip L, De Weireld, Guy, Vimont, Alexandre, Daturi, Marco, Chang, Jong-San
Format: Article
Language:English
Subjects:
Chemical Physics
Physics
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Summary:Hybrid porous solids, with their tunable structures, their multifunctional properties and their numerous applications, are currently topical, particularly in the domain of adsorption and storage of greenhouse gases. Most of the data reported so far concern the performances of these solids in this domain, particularly in terms of adsorbed amounts of gas but do not explain at the atomic level why and how adsorption and storage occur. From a combination of structural, spectroscopic, thermodynamic experiments and of molecular simulations, this tutorial review proposes answers to these open questions with a special emphasis on CO(2) and CH(4) storage by some rigid and flexible hybrid porous materials.
ISSN:0306-0012
1460-4744
DOI:10.1039/c0cs00040j