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Synthesis and physical properties of new surfactants based on ionic liquids: Improvement of thermal stability and mechanical behaviour of high density polyethylene nanocomposites
TEM micrographs of (a) PE/MMT-P I −, (b) PE/MMT-P Br −, (c) PE/MMT-P PF 6 - . [Display omitted] ► Synthesis of new surfactants for the olefinic matrices. ► Preparation of thermostable ionic liquid (IL) modified montmorillonites. ► Improvement of thermal and mechanical properties of nanocomposites. I...
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| Published in: | Journal of colloid and interface science 2011-02, Vol.354 (2), p.555-562 |
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| cites | cdi_FETCH-LOGICAL-c475t-d2ff178a5b12ee36d56727647595de3c9bea78d199e9908871c97d1a9b2303653 |
| container_end_page | 562 |
| container_issue | 2 |
| container_start_page | 555 |
| container_title | Journal of colloid and interface science |
| container_volume | 354 |
| creator | Livi, Sébastien Duchet-Rumeau, Jannick Pham, Thi Nhàn Gérard, Jean-François |
| description | TEM micrographs of (a) PE/MMT-P I
−, (b) PE/MMT-P Br
−, (c) PE/MMT-P
PF
6
-
.
[Display omitted]
► Synthesis of new surfactants for the olefinic matrices. ► Preparation of thermostable ionic liquid (IL) modified montmorillonites. ► Improvement of thermal and mechanical properties of nanocomposites.
Ionic liquids based on alkyltriphenyl phosphonium and dialkyl imidazolium cations with long alkyl chains have been synthesized and used as new surfactants for cationic exchange of layered silicates. The influence of the alkyl chain length and the chemical nature of the conteranion or of the cation on the thermal stability of these new intercalating agents and on imidazolium- (MMT-I) or phosphonium- (MMT-P) modified montmorillonites have been analyzed by thermogravimetric analysis (TGA). Thermoplastic nanocomposites based on these modified montmorillonites with a very low amount of nanofillers (1
wt.%) have been processed by melt mixing using a twin screw extruder. The distribution of the clay layers in a high density polyethylene (HDPE) matrix was characterized and finally the mechanical and thermal properties of the corresponding nanocomposites were determined. |
| doi_str_mv | 10.1016/j.jcis.2010.10.058 |
| format | article |
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−, (b) PE/MMT-P Br
−, (c) PE/MMT-P
PF
6
-
.
[Display omitted]
► Synthesis of new surfactants for the olefinic matrices. ► Preparation of thermostable ionic liquid (IL) modified montmorillonites. ► Improvement of thermal and mechanical properties of nanocomposites.
Ionic liquids based on alkyltriphenyl phosphonium and dialkyl imidazolium cations with long alkyl chains have been synthesized and used as new surfactants for cationic exchange of layered silicates. The influence of the alkyl chain length and the chemical nature of the conteranion or of the cation on the thermal stability of these new intercalating agents and on imidazolium- (MMT-I) or phosphonium- (MMT-P) modified montmorillonites have been analyzed by thermogravimetric analysis (TGA). Thermoplastic nanocomposites based on these modified montmorillonites with a very low amount of nanofillers (1
wt.%) have been processed by melt mixing using a twin screw extruder. The distribution of the clay layers in a high density polyethylene (HDPE) matrix was characterized and finally the mechanical and thermal properties of the corresponding nanocomposites were determined.</description><identifier>ISSN: 0021-9797</identifier><identifier>EISSN: 1095-7103</identifier><identifier>DOI: 10.1016/j.jcis.2010.10.058</identifier><identifier>PMID: 21084097</identifier><identifier>CODEN: JCISA5</identifier><language>eng</language><publisher>Amsterdam: Elsevier Inc</publisher><subject>Cationic exchange ; cationic surfactants ; cations ; Chemical Sciences ; Chemistry ; clay ; Exact sciences and technology ; General and physical chemistry ; High density ; Ionic liquids ; Material chemistry ; melting ; mixing ; Montmorillonite ; Nanocomposites ; Nanostructure ; Organoclay ; Polyethylene ; Polyethylenes ; Polymers ; silicates ; Surfactants ; Thermal properties ; Thermal stability ; thermogravimetry ; thermoplastics</subject><ispartof>Journal of colloid and interface science, 2011-02, Vol.354 (2), p.555-562</ispartof><rights>2010 Elsevier Inc.</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2010 Elsevier Inc. All rights reserved.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c475t-d2ff178a5b12ee36d56727647595de3c9bea78d199e9908871c97d1a9b2303653</citedby><cites>FETCH-LOGICAL-c475t-d2ff178a5b12ee36d56727647595de3c9bea78d199e9908871c97d1a9b2303653</cites><orcidid>0000-0002-1397-1434 ; 0000-0003-4959-982X ; 0000-0002-3096-2767</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27903,27904</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23931548$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21084097$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-00649298$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Livi, Sébastien</creatorcontrib><creatorcontrib>Duchet-Rumeau, Jannick</creatorcontrib><creatorcontrib>Pham, Thi Nhàn</creatorcontrib><creatorcontrib>Gérard, Jean-François</creatorcontrib><title>Synthesis and physical properties of new surfactants based on ionic liquids: Improvement of thermal stability and mechanical behaviour of high density polyethylene nanocomposites</title><title>Journal of colloid and interface science</title><addtitle>J Colloid Interface Sci</addtitle><description>TEM micrographs of (a) PE/MMT-P I
−, (b) PE/MMT-P Br
−, (c) PE/MMT-P
PF
6
-
.
[Display omitted]
► Synthesis of new surfactants for the olefinic matrices. ► Preparation of thermostable ionic liquid (IL) modified montmorillonites. ► Improvement of thermal and mechanical properties of nanocomposites.
Ionic liquids based on alkyltriphenyl phosphonium and dialkyl imidazolium cations with long alkyl chains have been synthesized and used as new surfactants for cationic exchange of layered silicates. The influence of the alkyl chain length and the chemical nature of the conteranion or of the cation on the thermal stability of these new intercalating agents and on imidazolium- (MMT-I) or phosphonium- (MMT-P) modified montmorillonites have been analyzed by thermogravimetric analysis (TGA). Thermoplastic nanocomposites based on these modified montmorillonites with a very low amount of nanofillers (1
wt.%) have been processed by melt mixing using a twin screw extruder. The distribution of the clay layers in a high density polyethylene (HDPE) matrix was characterized and finally the mechanical and thermal properties of the corresponding nanocomposites were determined.</description><subject>Cationic exchange</subject><subject>cationic surfactants</subject><subject>cations</subject><subject>Chemical Sciences</subject><subject>Chemistry</subject><subject>clay</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>High density</subject><subject>Ionic liquids</subject><subject>Material chemistry</subject><subject>melting</subject><subject>mixing</subject><subject>Montmorillonite</subject><subject>Nanocomposites</subject><subject>Nanostructure</subject><subject>Organoclay</subject><subject>Polyethylene</subject><subject>Polyethylenes</subject><subject>Polymers</subject><subject>silicates</subject><subject>Surfactants</subject><subject>Thermal properties</subject><subject>Thermal stability</subject><subject>thermogravimetry</subject><subject>thermoplastics</subject><issn>0021-9797</issn><issn>1095-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFksFu1DAQhiMEosvCC3AAX1DFYRfbWcdxxaWqgFZaiUPp2XLsSeNVYqd2siivxRPW2V32CCdLM9_8M-P5s-w9wWuCSfFlt95pG9cUHwJrzMoX2YJgwVac4PxltsCYkpXggl9kb2LcYUwIY-J1dkEJLjdY8EX2535yQwPRRqScQX0zRatVi_rgewiDhYh8jRz8RnEMtdKDckNElYpgkHfIemc1au3TaE28QnddqttDB26Yy5Jw6JJYHFRlWztMhx4d6Ea5Q5cKGrW3fgwz3djHBhlwcQZ7304wNFMLDpBTzmvf9T6lIL7NXtWqjfDu9C6zh-_fft3crrY_f9zdXG9XesPZsDK0rgkvFasIBcgLwwpOeZFyghnItahA8dIQIUAIXJacaMENUaKiOc4Lli-zz0fdRrWyD7ZTYZJeWXl7vZVzDONiI6go9ySxl0c27f80QhxkZ6OGtlUO_BhlyRhPX07Z_0lKcyZIGmGZ0SOpg48xQH0egmA5G0Du5GwAORtgjiUDpKIPJ_mx6sCcS_5ePAGfToCK6QR1UG7WOHO5yAnbzEIfj1ytvFSPITEP96lTgdPaJWGz0tcjAekIewtBRm3BaTA2gB6k8fZfkz4DbKPbNQ</recordid><startdate>20110215</startdate><enddate>20110215</enddate><creator>Livi, Sébastien</creator><creator>Duchet-Rumeau, Jannick</creator><creator>Pham, Thi Nhàn</creator><creator>Gérard, Jean-François</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-1397-1434</orcidid><orcidid>https://orcid.org/0000-0003-4959-982X</orcidid><orcidid>https://orcid.org/0000-0002-3096-2767</orcidid></search><sort><creationdate>20110215</creationdate><title>Synthesis and physical properties of new surfactants based on ionic liquids: Improvement of thermal stability and mechanical behaviour of high density polyethylene nanocomposites</title><author>Livi, Sébastien ; Duchet-Rumeau, Jannick ; Pham, Thi Nhàn ; Gérard, Jean-François</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c475t-d2ff178a5b12ee36d56727647595de3c9bea78d199e9908871c97d1a9b2303653</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Cationic exchange</topic><topic>cationic surfactants</topic><topic>cations</topic><topic>Chemical Sciences</topic><topic>Chemistry</topic><topic>clay</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>High density</topic><topic>Ionic liquids</topic><topic>Material chemistry</topic><topic>melting</topic><topic>mixing</topic><topic>Montmorillonite</topic><topic>Nanocomposites</topic><topic>Nanostructure</topic><topic>Organoclay</topic><topic>Polyethylene</topic><topic>Polyethylenes</topic><topic>Polymers</topic><topic>silicates</topic><topic>Surfactants</topic><topic>Thermal properties</topic><topic>Thermal stability</topic><topic>thermogravimetry</topic><topic>thermoplastics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Livi, Sébastien</creatorcontrib><creatorcontrib>Duchet-Rumeau, Jannick</creatorcontrib><creatorcontrib>Pham, Thi Nhàn</creatorcontrib><creatorcontrib>Gérard, Jean-François</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of colloid and interface science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Livi, Sébastien</au><au>Duchet-Rumeau, Jannick</au><au>Pham, Thi Nhàn</au><au>Gérard, Jean-François</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and physical properties of new surfactants based on ionic liquids: Improvement of thermal stability and mechanical behaviour of high density polyethylene nanocomposites</atitle><jtitle>Journal of colloid and interface science</jtitle><addtitle>J Colloid Interface Sci</addtitle><date>2011-02-15</date><risdate>2011</risdate><volume>354</volume><issue>2</issue><spage>555</spage><epage>562</epage><pages>555-562</pages><issn>0021-9797</issn><eissn>1095-7103</eissn><coden>JCISA5</coden><abstract>TEM micrographs of (a) PE/MMT-P I
−, (b) PE/MMT-P Br
−, (c) PE/MMT-P
PF
6
-
.
[Display omitted]
► Synthesis of new surfactants for the olefinic matrices. ► Preparation of thermostable ionic liquid (IL) modified montmorillonites. ► Improvement of thermal and mechanical properties of nanocomposites.
Ionic liquids based on alkyltriphenyl phosphonium and dialkyl imidazolium cations with long alkyl chains have been synthesized and used as new surfactants for cationic exchange of layered silicates. The influence of the alkyl chain length and the chemical nature of the conteranion or of the cation on the thermal stability of these new intercalating agents and on imidazolium- (MMT-I) or phosphonium- (MMT-P) modified montmorillonites have been analyzed by thermogravimetric analysis (TGA). Thermoplastic nanocomposites based on these modified montmorillonites with a very low amount of nanofillers (1
wt.%) have been processed by melt mixing using a twin screw extruder. The distribution of the clay layers in a high density polyethylene (HDPE) matrix was characterized and finally the mechanical and thermal properties of the corresponding nanocomposites were determined.</abstract><cop>Amsterdam</cop><pub>Elsevier Inc</pub><pmid>21084097</pmid><doi>10.1016/j.jcis.2010.10.058</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-1397-1434</orcidid><orcidid>https://orcid.org/0000-0003-4959-982X</orcidid><orcidid>https://orcid.org/0000-0002-3096-2767</orcidid></addata></record> |
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| ispartof | Journal of colloid and interface science, 2011-02, Vol.354 (2), p.555-562 |
| issn | 0021-9797 1095-7103 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_00649298v1 |
| source | ScienceDirect Freedom Collection |
| subjects | Cationic exchange cationic surfactants cations Chemical Sciences Chemistry clay Exact sciences and technology General and physical chemistry High density Ionic liquids Material chemistry melting mixing Montmorillonite Nanocomposites Nanostructure Organoclay Polyethylene Polyethylenes Polymers silicates Surfactants Thermal properties Thermal stability thermogravimetry thermoplastics |
| title | Synthesis and physical properties of new surfactants based on ionic liquids: Improvement of thermal stability and mechanical behaviour of high density polyethylene nanocomposites |
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