Clustomesogens: Liquid Crystal Materials Containing Transition-Metal Clusters

Shining red–NIR light: Bright red–NIR photoluminescent liquid crystals were obtained by grafting six promesogenic units onto an octahedral molybdenum cluster core (see picture). This hybrid self‐arranges in a lamellar structure over a wide range of temperatures to give the first clustomesogen.

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2010-04, Vol.49 (19), p.3351-3355
Main Authors: Molard, Yann, Dorson, Frederick, Cîrcu, Viorel, Roisnel, Thierry, Artzner, Franck, Cordier, Stéphane
Format: Article
Language:English
Subjects:
Chemical Sciences
cluster compounds
liquid crystals
luminescence
Material chemistry
metallomesogens
organic-inorganic hybrid composites
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Description
Summary:Shining red–NIR light: Bright red–NIR photoluminescent liquid crystals were obtained by grafting six promesogenic units onto an octahedral molybdenum cluster core (see picture). This hybrid self‐arranges in a lamellar structure over a wide range of temperatures to give the first clustomesogen.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201000325