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Study of morphological and mechanical performance of amine-cured glassy epoxy-clay nanocomposites
The effect of three different alkylammonium‐modified montmorillonite on morphological and mechanical properties of glassy epoxy‐amine nanocomposites is reported. Small amounts of clays
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Published in: | Journal of applied polymer science 2012-06, Vol.124 (6), p.4729-4739 |
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container_title | Journal of applied polymer science |
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creator | Mouloud, A. Cherif, R. Fellahi, S. Grohens, Y. Pillin, I. |
description | The effect of three different alkylammonium‐modified montmorillonite on morphological and mechanical properties of glassy epoxy‐amine nanocomposites is reported. Small amounts of clays |
doi_str_mv | 10.1002/app.35520 |
format | article |
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Small amounts of clays <10 phr (part per hundred of resin) were used in each system of nanocomposite. The morphology of the prepared nanocomposites was performed by means of X‐ray diffraction and transmission electron microscopy. Differential scanning calorimetry (DSC) was used to investigate the glass transition temperatures (Tg). Mechanical properties were based on tensile characteristics (Young's modulus), impact strength, and fracture toughness. The measured moduli were compared to theoretical predictions. Scanning electron microscopy was used to study the morphological structure of the fracture surfaces of impacted specimens. It was found that at a low content of 2 phr (1.2 wt %) of nanoclays, the impact strength and the fracture toughness were improved by 77 and 90% respectively, comparatively to the neat epoxy, whereas DSC revealed a reduction of the Tg of nanocomposites. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.35520</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Composites ; Differential scanning calorimetry ; epoxy nanocomposites ; Exact sciences and technology ; Forms of application and semi-finished materials ; Fracture toughness ; Glassy ; Impact strength ; Materials science ; Mechanical properties ; montmorillonite ; morphology ; Nanocomposites ; Nanostructure ; Polymer industry, paints, wood ; Polymers ; Reduction ; Technology of polymers ; toughness</subject><ispartof>Journal of applied polymer science, 2012-06, Vol.124 (6), p.4729-4739</ispartof><rights>Copyright © 2011 Wiley Periodicals, Inc.</rights><rights>2014 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4320-ff138bae5c4645bb96dcaf95418f6b6d4b36ee77a6c3d11a145a69d144766ccb3</citedby><cites>FETCH-LOGICAL-c4320-ff138bae5c4645bb96dcaf95418f6b6d4b36ee77a6c3d11a145a69d144766ccb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27923,27924</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25641988$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-00715062$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Mouloud, A.</creatorcontrib><creatorcontrib>Cherif, R.</creatorcontrib><creatorcontrib>Fellahi, S.</creatorcontrib><creatorcontrib>Grohens, Y.</creatorcontrib><creatorcontrib>Pillin, I.</creatorcontrib><title>Study of morphological and mechanical performance of amine-cured glassy epoxy-clay nanocomposites</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>The effect of three different alkylammonium‐modified montmorillonite on morphological and mechanical properties of glassy epoxy‐amine nanocomposites is reported. Small amounts of clays <10 phr (part per hundred of resin) were used in each system of nanocomposite. The morphology of the prepared nanocomposites was performed by means of X‐ray diffraction and transmission electron microscopy. Differential scanning calorimetry (DSC) was used to investigate the glass transition temperatures (Tg). Mechanical properties were based on tensile characteristics (Young's modulus), impact strength, and fracture toughness. The measured moduli were compared to theoretical predictions. Scanning electron microscopy was used to study the morphological structure of the fracture surfaces of impacted specimens. It was found that at a low content of 2 phr (1.2 wt %) of nanoclays, the impact strength and the fracture toughness were improved by 77 and 90% respectively, comparatively to the neat epoxy, whereas DSC revealed a reduction of the Tg of nanocomposites. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011</description><subject>Applied sciences</subject><subject>Composites</subject><subject>Differential scanning calorimetry</subject><subject>epoxy nanocomposites</subject><subject>Exact sciences and technology</subject><subject>Forms of application and semi-finished materials</subject><subject>Fracture toughness</subject><subject>Glassy</subject><subject>Impact strength</subject><subject>Materials science</subject><subject>Mechanical properties</subject><subject>montmorillonite</subject><subject>morphology</subject><subject>Nanocomposites</subject><subject>Nanostructure</subject><subject>Polymer industry, paints, wood</subject><subject>Polymers</subject><subject>Reduction</subject><subject>Technology of polymers</subject><subject>toughness</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp1kUtv1DAUhSMEEkPpgn8QCSHBIq0dv5LlqCrTwohWtMDSunHsjosTB3tCm3-P0ylTCYmVZfs75z5Olr3B6AgjVB7DMBwRxkr0LFtgVIuC8rJ6ni3SHy6qumYvs1cx3iKEMUN8kcHVdmyn3Ju882HYeOdvrAKXQ9_mnVYb6B-ugw7Ghw56pWcWOtvrQo1Bt_mNgxinXA_-fiqUgynvoffKd4OPdqvj6-yFARf14eN5kH37eHp9clasL1bnJ8t1oSgpUWEMJlUDminKKWuamrcKTM0orgxveEsbwrUWArgiLcaAKQNet5hSwblSDTnIPux8N-DkEGwHYZIerDxbruX8hpCYZy5_48S-37FD8L9GHbeys1Fp56DXfowSp7K0FCUnCX37D3rrx9CnSRKFBUKEkeqpuAo-xqDNvgOM5ByMTMHIh2AS--7REWLarQlpqzbuBSXjFNfV7Hm84-6s09P_DeXy8vKvc7FT2LjV93sFhJ-SCyKY_PFlJfmn66-fv69WEpE_JNerKQ</recordid><startdate>20120615</startdate><enddate>20120615</enddate><creator>Mouloud, A.</creator><creator>Cherif, R.</creator><creator>Fellahi, S.</creator><creator>Grohens, Y.</creator><creator>Pillin, I.</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>1XC</scope></search><sort><creationdate>20120615</creationdate><title>Study of morphological and mechanical performance of amine-cured glassy epoxy-clay nanocomposites</title><author>Mouloud, A. ; Cherif, R. ; Fellahi, S. ; Grohens, Y. ; Pillin, I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4320-ff138bae5c4645bb96dcaf95418f6b6d4b36ee77a6c3d11a145a69d144766ccb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Applied sciences</topic><topic>Composites</topic><topic>Differential scanning calorimetry</topic><topic>epoxy nanocomposites</topic><topic>Exact sciences and technology</topic><topic>Forms of application and semi-finished materials</topic><topic>Fracture toughness</topic><topic>Glassy</topic><topic>Impact strength</topic><topic>Materials science</topic><topic>Mechanical properties</topic><topic>montmorillonite</topic><topic>morphology</topic><topic>Nanocomposites</topic><topic>Nanostructure</topic><topic>Polymer industry, paints, wood</topic><topic>Polymers</topic><topic>Reduction</topic><topic>Technology of polymers</topic><topic>toughness</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mouloud, A.</creatorcontrib><creatorcontrib>Cherif, R.</creatorcontrib><creatorcontrib>Fellahi, S.</creatorcontrib><creatorcontrib>Grohens, Y.</creatorcontrib><creatorcontrib>Pillin, I.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mouloud, A.</au><au>Cherif, R.</au><au>Fellahi, S.</au><au>Grohens, Y.</au><au>Pillin, I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study of morphological and mechanical performance of amine-cured glassy epoxy-clay nanocomposites</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2012-06-15</date><risdate>2012</risdate><volume>124</volume><issue>6</issue><spage>4729</spage><epage>4739</epage><pages>4729-4739</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>The effect of three different alkylammonium‐modified montmorillonite on morphological and mechanical properties of glassy epoxy‐amine nanocomposites is reported. Small amounts of clays <10 phr (part per hundred of resin) were used in each system of nanocomposite. The morphology of the prepared nanocomposites was performed by means of X‐ray diffraction and transmission electron microscopy. Differential scanning calorimetry (DSC) was used to investigate the glass transition temperatures (Tg). Mechanical properties were based on tensile characteristics (Young's modulus), impact strength, and fracture toughness. The measured moduli were compared to theoretical predictions. Scanning electron microscopy was used to study the morphological structure of the fracture surfaces of impacted specimens. It was found that at a low content of 2 phr (1.2 wt %) of nanoclays, the impact strength and the fracture toughness were improved by 77 and 90% respectively, comparatively to the neat epoxy, whereas DSC revealed a reduction of the Tg of nanocomposites. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.35520</doi><tpages>11</tpages></addata></record> |
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subjects | Applied sciences Composites Differential scanning calorimetry epoxy nanocomposites Exact sciences and technology Forms of application and semi-finished materials Fracture toughness Glassy Impact strength Materials science Mechanical properties montmorillonite morphology Nanocomposites Nanostructure Polymer industry, paints, wood Polymers Reduction Technology of polymers toughness |
title | Study of morphological and mechanical performance of amine-cured glassy epoxy-clay nanocomposites |
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