Electrofluorochromism of a ruthenium complex investigated by time resolved TIRF microscopy coupled to an electrochemical cell

This paper describes the use of TIRF microscopy coupled to electrochemistry to investigate the electrofluorochromic properties of a new bipyidine–phenanthroline ruthenium complex. A reversible electrochemical modulation of luminescence is observed when applying potential steps between the reduced em...

Full description

Saved in:
Bibliographic Details
Published in:Electrochemistry communications 2012-07, Vol.20, p.83-87
Main Authors: Miomandre, F., Pansu, R.B., Audibert, J.F., Guerlin, A., Mayer, C.R.
Format: Article
Language:English
Subjects:
Chemical Sciences
Chemistry
Electrochemistry
Exact sciences and technology
Fluorescence
General and physical chemistry
Lifetime
Microscopy
Miscellaneous (electroosmosis, electrophoresis, electrochromism, electrocrystallization, ...)
or physical chemistry
Ruthenium
Theoretical and
TIRF
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c436t-535e82202496fef3205d10de765d168a36645f57e9c8aa74aced85fe0688d4473
cites cdi_FETCH-LOGICAL-c436t-535e82202496fef3205d10de765d168a36645f57e9c8aa74aced85fe0688d4473
container_end_page 87
container_issue
container_start_page 83
container_title Electrochemistry communications
container_volume 20
creator Miomandre, F.
Pansu, R.B.
Audibert, J.F.
Guerlin, A.
Mayer, C.R.
description This paper describes the use of TIRF microscopy coupled to electrochemistry to investigate the electrofluorochromic properties of a new bipyidine–phenanthroline ruthenium complex. A reversible electrochemical modulation of luminescence is observed when applying potential steps between the reduced emitting state and the oxidized non emitting one. Variations of intensity and lifetimes along the potential steps are analyzed to understand the mechanism of this switch. It is shown that a quenching mechanism occurs upon electrooxidation that accounts for the fast luminescence switch process. [Display omitted] ► Application of TIRF microscopy coupled to electrochemistry to the luminescence switch of an inorganic compound. ► Luminescence intensity, lifetimes, spectra and images are recorded. ► Luminescence intensity and lifetimes are modulated reversibly by the electrode potential.
doi_str_mv 10.1016/j.elecom.2012.03.030
format article
fullrecord <record><control><sourceid>elsevier_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_00751877v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S1388248112001294</els_id><sourcerecordid>S1388248112001294</sourcerecordid><originalsourceid>FETCH-LOGICAL-c436t-535e82202496fef3205d10de765d168a36645f57e9c8aa74aced85fe0688d4473</originalsourceid><addsrcrecordid>eNp9kE-LFDEQxRtRcF39Bh5y8eChx8qfTqcvwrLsugsDgqznENMVJ0O6MyQ9g3Pwu28NLXsUCioU71eV95rmI4cNB66_7DeY0OdpI4CLDUgqeNVccdPLlg8gXtNbGtMKZfjb5l2teyDhMMir5u8dkUvJIR1zyX5X8hTrxHJgjpXjssM5HidGuw8J_7A4n7Au8bdbcGS_zmyJE7KCNacTDZ4ef9yzKfqSq8-HM1FHoka2ZOZmhushv0OSuMQ8pvS-eRNcqvjhX79uft7fPd0-tNvv3x5vb7atV1IvbSc7NEKAUIMOGKSAbuQwYq-pa-Ok1qoLXY-DN871ynkcTRcQtDGjUr28bj6ve3cu2UOJkytnm120Dzdbe5kB9B3F1Z84adWqvfioBcMLwMFe4rZ7u8ZtL3FbkFRA2KcVO7hK9kJxs4_1hRUalFDckO7rqkPye4pYbPURZ_pxLBSQHXP8_6FnjXiZWw</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Electrofluorochromism of a ruthenium complex investigated by time resolved TIRF microscopy coupled to an electrochemical cell</title><source>Elsevier</source><creator>Miomandre, F. ; Pansu, R.B. ; Audibert, J.F. ; Guerlin, A. ; Mayer, C.R.</creator><creatorcontrib>Miomandre, F. ; Pansu, R.B. ; Audibert, J.F. ; Guerlin, A. ; Mayer, C.R.</creatorcontrib><description>This paper describes the use of TIRF microscopy coupled to electrochemistry to investigate the electrofluorochromic properties of a new bipyidine–phenanthroline ruthenium complex. A reversible electrochemical modulation of luminescence is observed when applying potential steps between the reduced emitting state and the oxidized non emitting one. Variations of intensity and lifetimes along the potential steps are analyzed to understand the mechanism of this switch. It is shown that a quenching mechanism occurs upon electrooxidation that accounts for the fast luminescence switch process. [Display omitted] ► Application of TIRF microscopy coupled to electrochemistry to the luminescence switch of an inorganic compound. ► Luminescence intensity, lifetimes, spectra and images are recorded. ► Luminescence intensity and lifetimes are modulated reversibly by the electrode potential.</description><identifier>ISSN: 1388-2481</identifier><identifier>EISSN: 1873-1902</identifier><identifier>DOI: 10.1016/j.elecom.2012.03.030</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Chemical Sciences ; Chemistry ; Electrochemistry ; Exact sciences and technology ; Fluorescence ; General and physical chemistry ; Lifetime ; Microscopy ; Miscellaneous (electroosmosis, electrophoresis, electrochromism, electrocrystallization, ...) ; or physical chemistry ; Ruthenium ; Theoretical and ; TIRF</subject><ispartof>Electrochemistry communications, 2012-07, Vol.20, p.83-87</ispartof><rights>2012 Elsevier B.V.</rights><rights>2014 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c436t-535e82202496fef3205d10de765d168a36645f57e9c8aa74aced85fe0688d4473</citedby><cites>FETCH-LOGICAL-c436t-535e82202496fef3205d10de765d168a36645f57e9c8aa74aced85fe0688d4473</cites><orcidid>0000-0002-5588-3950 ; 0000-0003-2001-9473</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=26042418$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-00751877$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Miomandre, F.</creatorcontrib><creatorcontrib>Pansu, R.B.</creatorcontrib><creatorcontrib>Audibert, J.F.</creatorcontrib><creatorcontrib>Guerlin, A.</creatorcontrib><creatorcontrib>Mayer, C.R.</creatorcontrib><title>Electrofluorochromism of a ruthenium complex investigated by time resolved TIRF microscopy coupled to an electrochemical cell</title><title>Electrochemistry communications</title><description>This paper describes the use of TIRF microscopy coupled to electrochemistry to investigate the electrofluorochromic properties of a new bipyidine–phenanthroline ruthenium complex. A reversible electrochemical modulation of luminescence is observed when applying potential steps between the reduced emitting state and the oxidized non emitting one. Variations of intensity and lifetimes along the potential steps are analyzed to understand the mechanism of this switch. It is shown that a quenching mechanism occurs upon electrooxidation that accounts for the fast luminescence switch process. [Display omitted] ► Application of TIRF microscopy coupled to electrochemistry to the luminescence switch of an inorganic compound. ► Luminescence intensity, lifetimes, spectra and images are recorded. ► Luminescence intensity and lifetimes are modulated reversibly by the electrode potential.</description><subject>Chemical Sciences</subject><subject>Chemistry</subject><subject>Electrochemistry</subject><subject>Exact sciences and technology</subject><subject>Fluorescence</subject><subject>General and physical chemistry</subject><subject>Lifetime</subject><subject>Microscopy</subject><subject>Miscellaneous (electroosmosis, electrophoresis, electrochromism, electrocrystallization, ...)</subject><subject>or physical chemistry</subject><subject>Ruthenium</subject><subject>Theoretical and</subject><subject>TIRF</subject><issn>1388-2481</issn><issn>1873-1902</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp9kE-LFDEQxRtRcF39Bh5y8eChx8qfTqcvwrLsugsDgqznENMVJ0O6MyQ9g3Pwu28NLXsUCioU71eV95rmI4cNB66_7DeY0OdpI4CLDUgqeNVccdPLlg8gXtNbGtMKZfjb5l2teyDhMMir5u8dkUvJIR1zyX5X8hTrxHJgjpXjssM5HidGuw8J_7A4n7Au8bdbcGS_zmyJE7KCNacTDZ4ef9yzKfqSq8-HM1FHoka2ZOZmhushv0OSuMQ8pvS-eRNcqvjhX79uft7fPd0-tNvv3x5vb7atV1IvbSc7NEKAUIMOGKSAbuQwYq-pa-Ok1qoLXY-DN871ynkcTRcQtDGjUr28bj6ve3cu2UOJkytnm120Dzdbe5kB9B3F1Z84adWqvfioBcMLwMFe4rZ7u8ZtL3FbkFRA2KcVO7hK9kJxs4_1hRUalFDckO7rqkPye4pYbPURZ_pxLBSQHXP8_6FnjXiZWw</recordid><startdate>20120701</startdate><enddate>20120701</enddate><creator>Miomandre, F.</creator><creator>Pansu, R.B.</creator><creator>Audibert, J.F.</creator><creator>Guerlin, A.</creator><creator>Mayer, C.R.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-5588-3950</orcidid><orcidid>https://orcid.org/0000-0003-2001-9473</orcidid></search><sort><creationdate>20120701</creationdate><title>Electrofluorochromism of a ruthenium complex investigated by time resolved TIRF microscopy coupled to an electrochemical cell</title><author>Miomandre, F. ; Pansu, R.B. ; Audibert, J.F. ; Guerlin, A. ; Mayer, C.R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c436t-535e82202496fef3205d10de765d168a36645f57e9c8aa74aced85fe0688d4473</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Chemical Sciences</topic><topic>Chemistry</topic><topic>Electrochemistry</topic><topic>Exact sciences and technology</topic><topic>Fluorescence</topic><topic>General and physical chemistry</topic><topic>Lifetime</topic><topic>Microscopy</topic><topic>Miscellaneous (electroosmosis, electrophoresis, electrochromism, electrocrystallization, ...)</topic><topic>or physical chemistry</topic><topic>Ruthenium</topic><topic>Theoretical and</topic><topic>TIRF</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Miomandre, F.</creatorcontrib><creatorcontrib>Pansu, R.B.</creatorcontrib><creatorcontrib>Audibert, J.F.</creatorcontrib><creatorcontrib>Guerlin, A.</creatorcontrib><creatorcontrib>Mayer, C.R.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Electrochemistry communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Miomandre, F.</au><au>Pansu, R.B.</au><au>Audibert, J.F.</au><au>Guerlin, A.</au><au>Mayer, C.R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrofluorochromism of a ruthenium complex investigated by time resolved TIRF microscopy coupled to an electrochemical cell</atitle><jtitle>Electrochemistry communications</jtitle><date>2012-07-01</date><risdate>2012</risdate><volume>20</volume><spage>83</spage><epage>87</epage><pages>83-87</pages><issn>1388-2481</issn><eissn>1873-1902</eissn><abstract>This paper describes the use of TIRF microscopy coupled to electrochemistry to investigate the electrofluorochromic properties of a new bipyidine–phenanthroline ruthenium complex. A reversible electrochemical modulation of luminescence is observed when applying potential steps between the reduced emitting state and the oxidized non emitting one. Variations of intensity and lifetimes along the potential steps are analyzed to understand the mechanism of this switch. It is shown that a quenching mechanism occurs upon electrooxidation that accounts for the fast luminescence switch process. [Display omitted] ► Application of TIRF microscopy coupled to electrochemistry to the luminescence switch of an inorganic compound. ► Luminescence intensity, lifetimes, spectra and images are recorded. ► Luminescence intensity and lifetimes are modulated reversibly by the electrode potential.</abstract><cop>Lausanne</cop><cop>Amsterdam</cop><cop>New York, NY</cop><pub>Elsevier B.V</pub><doi>10.1016/j.elecom.2012.03.030</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0002-5588-3950</orcidid><orcidid>https://orcid.org/0000-0003-2001-9473</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1388-2481
ispartof Electrochemistry communications, 2012-07, Vol.20, p.83-87
issn 1388-2481
1873-1902
language eng
recordid cdi_hal_primary_oai_HAL_hal_00751877v1
source Elsevier
subjects Chemical Sciences
Chemistry
Electrochemistry
Exact sciences and technology
Fluorescence
General and physical chemistry
Lifetime
Microscopy
Miscellaneous (electroosmosis, electrophoresis, electrochromism, electrocrystallization, ...)
or physical chemistry
Ruthenium
Theoretical and
TIRF
title Electrofluorochromism of a ruthenium complex investigated by time resolved TIRF microscopy coupled to an electrochemical cell
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-02T22%3A57%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-elsevier_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Electrofluorochromism%20of%20a%20ruthenium%20complex%20investigated%20by%20time%20resolved%20TIRF%20microscopy%20coupled%20to%20an%20electrochemical%20cell&rft.jtitle=Electrochemistry%20communications&rft.au=Miomandre,%20F.&rft.date=2012-07-01&rft.volume=20&rft.spage=83&rft.epage=87&rft.pages=83-87&rft.issn=1388-2481&rft.eissn=1873-1902&rft_id=info:doi/10.1016/j.elecom.2012.03.030&rft_dat=%3Celsevier_hal_p%3ES1388248112001294%3C/elsevier_hal_p%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c436t-535e82202496fef3205d10de765d168a36645f57e9c8aa74aced85fe0688d4473%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true