A multi-technique approach to the characterization of iron phosphide tribofilm

• Published in: Thin solid films 2012-12, Vol.524, p.191-196
• Main Authors: Philippon, D., De Barros-Bouchet, M.-I., Le Mogne, Th, Vacher, B., Lerasle, O., Martin, J.-M.
• Format: Article
• Language: English
• Subjects: Composition and phase identification; Condensed matter: structure, mechanical and thermal properties; Cross sections; Engineering Sciences; Exact sciences and technology; Focus ion beam; Gas phases; Iron phosphide; Materials; Nucleation; Phosphides; Physics; Steels; Structural steels; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties); Thin film structure and morphology; Transmission electron microscopy; Tribological films; X-ray photoelectron spectroscopy
• ISSN: 0040-6090; 1879-2731
• DOI: 10.1016/j.tsf.2012.10.009

Tribofilms, formed by tribochemical reactions between steel surface and trimethylphosphite in gas phase, have been characterized by various structural and analytical techniques including transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and energy dispersive spectroscopy (EDS). Focus ion beam technique has been used to prepare cross-sections of the tribofilm for further TEM and EDS analyses. Cross-sectional views of tribofilms obtained by gas phase lubrication show that tribofilm has an inhomogeneous thickness ranging from 10 to 50nm and is amorphous. Complementary XPS and EDS analyses confirm the formation of various iron phosphides as the major component of the tribofilms, with a preferential nucleation of Fe3P stoichiometry at the interface between steel and tribofilm. ► Tribofilm was formed with phosphite lubricant additives. ► Cross-section of the tribofilm was investigated. ► Amorphous iron phosphide tribofilm is formed. ► Stoichiometry of iron phosphide changed at the interface with steel substrate.