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Experimental and multiscale modeling of thermal conductivity and elastic properties of PLA/expanded graphite polymer nanocomposites

► Poly-lactide/expanded graphite nanocomposites are fabricated. ► Thermal conductivity and elastic properties are characterized. ► Molecular dynamics simulations are used to evaluate expanded graphite properties. ► Experimental results are compared with hierarchical multiscale procedures. We develop...

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Published in:Thermochimica acta 2013-01, Vol.552 (20), p.106-113
Main Authors: Mortazavi, Bohayra, Hassouna, Fatima, Laachachi, Abdelghani, Rajabpour, Ali, Ahzi, Said, Chapron, David, Toniazzo, Valérie, Ruch, David
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container_title Thermochimica acta
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creator Mortazavi, Bohayra
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Ruch, David
description ► Poly-lactide/expanded graphite nanocomposites are fabricated. ► Thermal conductivity and elastic properties are characterized. ► Molecular dynamics simulations are used to evaluate expanded graphite properties. ► Experimental results are compared with hierarchical multiscale procedures. We developed experimental as well as theoretically based hierarchical multiscale procedures for the evaluation of effective elastic modulus and thermal conductivity of poly-lactide (PLA)/expanded graphite (EG) nanocomposites. The incorporation of EG fillers into PLA was carried out by a twin-screw micro-extruder. The dispersion/delamination of EG in PLA was studied using Raman spectroscopy, SEM and TEM. In the multiscale modeling, the thermal conductivity constants and stiffness tensor of EG were first acquired by the means of molecular dynamics (MD) simulations. Using the fillers’ properties obtained by the MD, we developed finite elements (FE) models to evaluate the effective thermal conductivity and elastic modulus of PLA/EG nanocomposites. Our results, for a wide range of temperatures revealed the efficiency in thermal and mechanical reinforcement of PLA by incorporation of EG nanoparticles.
doi_str_mv 10.1016/j.tca.2012.11.017
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subjects Chemical thermodynamics
Chemistry
Computer simulation
delamination
Elastic modulus
Exact sciences and technology
Expanded graphite
Finite element method
General and physical chemistry
General. Theory
graphene
Graphite
Heat transfer
Mathematical analysis
modulus of elasticity
molecular dynamics
Multiscale
Nanocomposites
nanoparticles
Physics
polymer nanocomposites
Raman spectroscopy
scanning electron microscopy
temperature
Thermal conductivity
transmission electron microscopy
title Experimental and multiscale modeling of thermal conductivity and elastic properties of PLA/expanded graphite polymer nanocomposites
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