Ruthenium( ii )-catalyzed selective monoarylation in water and sequential functionalisations of C–H bonds

The ruthenium(ii)-phosphine catalyst RuCl sub(2)(PPh sub(3))(p -cymene) operating water selectively leads to orthomonoarylation, with arylchlorides and heteroarylhalides, of functional arenes. Further catalytic heteroarylation with Ru(OAc) sub(2)(p-cymene) in water produces mixed bifunctional deriva...

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Bibliographic Details
Published in:Green chemistry : an international journal and green chemistry resource : GC 2013-01, Vol.15 (1), p.67-71
Main Authors: Arockiam, Percia B, Fischmeister, Cedric, Bruneau, Christian, Dixneuf, Pierre H
Format: Article
Language:English
Subjects:
Catalysis
Catalysts
Chemical Sciences
Derivatives
Other
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Summary:The ruthenium(ii)-phosphine catalyst RuCl sub(2)(PPh sub(3))(p -cymene) operating water selectively leads to orthomonoarylation, with arylchlorides and heteroarylhalides, of functional arenes. Further catalytic heteroarylation with Ru(OAc) sub(2)(p-cymene) in water produces mixed bifunctional derivatives.
ISSN:1463-9262
1463-9270
DOI:10.1039/c2gc36222h