Anti-Markovnikov additions to N-allylic derivatives involving ammonium-carbenium superelectrophiles

Anti-Markovnikov additions to non-conjugated unsaturated amines in superacid are reported. In situ NMR studies, DFT calculations and labelled substrates reactions support the involvement of new ammonium-carbenium superelectrophiles in this original process.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-06, Vol.48 (47), p.5877-5879
Main Authors: Compain, Guillaume, Martin-Mingot, Agnès, Frapper, Gilles, Bachmann, Christian, Jouannetaud, Marie-Paule, Thibaudeau, Sébastien
Format: Article
Language:English
Subjects:
Amines
Catalysis
Chemical Sciences
Derivatives
Mathematical analysis
Organic chemistry
Other
Unsaturated
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Description
Summary:Anti-Markovnikov additions to non-conjugated unsaturated amines in superacid are reported. In situ NMR studies, DFT calculations and labelled substrates reactions support the involvement of new ammonium-carbenium superelectrophiles in this original process.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc32246c