Flow electrochemical analyses of zinc by stripping voltammetry on graphite felt electrode

• Published in: Talanta (Oxford) 2012-08, Vol.98, p.152-156
• Main Authors: Feier, B., Floner, D., Cristea, C., Bodoki, E., Sandulescu, R., Geneste, F.
• Format: Article
• Language: English
• Subjects: Analytical chemistry; Anodic stripping voltammetry; Cations, Divalent - chemistry; Chemical Sciences; Chemistry; Deposition; Electrochemical methods; Electrochemical Techniques; Electrodes; Exact sciences and technology; Flow analysis; Fresh Water - chemistry; General, instrumentation; Graphite; Graphite - chemistry; Graphite felt; Material chemistry; Percolation; Porosity; Porous electrode; Sensitivity and Specificity; Sensors; Stripping; Trace analysis; Water Pollutants, Chemical - analysis; Zinc; Zinc - analysis
• ISSN: 0039-9140; 1873-3573
• DOI: 10.1016/j.talanta.2012.06.063

A flow sensor for trace analysis of zinc, using graphite felt as working electrode is reported here. A flow cell, well-adapted to 3-D porous electrodes and capable to do both the preconcentration step at a cathodic potential and the stripping of the zinc was successfully developed. It was demonstrated that this cell allows to obtain better electrochemical signals for Zn2+ compared to a standard three-electrodes cell and that the percolation during accumulation increases the kinetics of electrodeposition. The influence on Zn2+ signal of the deposition potential, the time of deposition and the flow rate was studied. The resulting sensor shows a linear response towards Zn2+ with a linear range of 10−6–10−4M and a limit of detection of 5×10−7M for an analysis time of 5min. The interferences study showed that the Cr3+, Pb2+, Cd2+ ions have a small effect on the Zn electrochemical signal, whereas Fe3+, Cu2+, Co2+ and Ni2+ ions strongly influence it. The electrode was tested on real samples (tap water spiked with Zn2+, food supplement) with a good recovery by applying the standard addition method. ► Detection of zinc with a flow electroanalytical system. ► Enhancement of the kinetics of electrodeposition by the flow system. ► Flow electrochemical cell with graphite felt electrode for heavy metals analyses. ► Good recovery values on real samples analyses.