Exploiting Non-Innocent Ligands to Prepare Masked Palladium(0) Complexes

Is it or isn't it: Reaction of [PdMe2(tmeda)] with pyridyl‐N‐di(tert‐butyl)phosphinoimine spontaneously affords an unusual bimetallic palladium(I) ligand‐based biradical complex, which behaves as a “masked” form of Pd0 in its reactions with neutral ligands and chlorobenzene.

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2010-09, Vol.49 (39), p.7040-7044
Main Authors: Smith, Dan A, Batsanov, Andrei S, Costuas, Karine, Edge, Ruth, Apperley, David C, Collison, David, Halet, Jean-François, Howard, Judith A.K, Dyer, Philip W
Format: Article
Language:English
Subjects:
Chemical Sciences
coordination chemistry
Inorganic chemistry
N ligands
non-innocent ligands
or physical chemistry
P,N ligands
palladium
redox reactions
Theoretical and
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Summary:Is it or isn't it: Reaction of [PdMe2(tmeda)] with pyridyl‐N‐di(tert‐butyl)phosphinoimine spontaneously affords an unusual bimetallic palladium(I) ligand‐based biradical complex, which behaves as a “masked” form of Pd0 in its reactions with neutral ligands and chlorobenzene.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201003946