Photo- and thermo-induced spin crossover in a cyanide-bridged {Mo(V)2Fe(II)2} rhombus molecule

The self-assembly of [Mo(V)(CN)8](3-) and [Fe(II)(bik)2(S)2](2+) affords a cyanide-bridged {Mo(V)2Fe(II)2} rhombus molecule that shows photomagnetic effect under laser light irradiation at low temperature and exhibits thermo-induced spin crossover near ambient temperature.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (22), p.2893-2895
Main Authors: Mondal, Abhishake, Li, Yanling, Chamoreau, Lise-Marie, Seuleiman, Mannan, Rechignat, Lionel, Bousseksou, Azzedine, Boillot, Marie-Laure, Lescouëzec, Rodrigue
Format: Article
Language:English
Subjects:
Ambient temperature
Chemical Sciences
Coordination chemistry
Crossovers
Lasers
Light irradiation
Photomagnetic effects
Self assembly
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Summary:The self-assembly of [Mo(V)(CN)8](3-) and [Fe(II)(bik)2(S)2](2+) affords a cyanide-bridged {Mo(V)2Fe(II)2} rhombus molecule that shows photomagnetic effect under laser light irradiation at low temperature and exhibits thermo-induced spin crossover near ambient temperature.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc49164a