Role of Glucose in Enhancing Stability of Aqueous Silica Gels Against Dehydration

• Published in: Journal of physical chemistry (1952) 2012-05, Vol.116 (17), p.9481-9486
• Main Authors: Lelong, Gérald, Heyd, Rodolphe, Charalambopoulou, Georgia, Steriotis, Theodore, Brandt, Astrid, Beck, Kevin, Vayer, Marylène, Price, David L, Brady, John W, Saboungi, Marie-Louise
• Format: Article
• Language: English
• Subjects: Condensed matter: structure, mechanical and thermal properties; Exact sciences and technology; General Physics; Physics; Structure and morphology; thickness; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties); Thin film structure and morphology
• ISSN: 1932-7447; 0022-3654; 1932-7455; 1541-5740
• DOI: 10.1021/jp208377t

The microstructure evolution of confined glucose solutions in silica gels can provide insights into the effect of sugars in protecting living organisms under extreme dehydration conditions. Aqueous silica gels with relatively small pore sizes capable of deforming under changes in environmental conditions are used here as a model system. In situ monitoring of the dehydration process – with and without the presence of sugar molecules – by optical photography, gravimetric measurements, small-angle neutron scattering, and atomic force microscopy reveals that sugar plays a crucial role in the mechanics and protection of the gel. In the absence of sugar, dehydration leads to considerable degradation, whereas the incorporation of large doses of glucose maintains the stability and robustness of the structure. A model is proposed to explain the time dependence of the dehydration process.