Loading…

Electron irradiation of nuclear graphite studied by transmission electron microscopy and electron energy loss spectroscopy

Structural and chemical bonding changes in nuclear graphite have been investigated during in-situ electron irradiation in a transmission electron microscope (TEM); electron beam irradiation has been employed as a surrogate for neutron irradiation of nuclear grade graphite in nuclear reactors. This p...

Full description

Saved in:
Bibliographic Details
Published in:Carbon (New York) 2015-03, Vol.83, p.106-117
Main Authors: Mironov, B.E., Freeman, H.M., Brown, A.P., Hage, F.S., Scott, A.J., Westwood, A.V.K., Da Costa, J.-P., Weisbecker, P., Brydson, R.M.D.
Format: Article
Language:English
Subjects:
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c485t-d170c2f7e22211d4ee28b53ef149b36be2885ef18e8276265481f24b6f7f71383
cites cdi_FETCH-LOGICAL-c485t-d170c2f7e22211d4ee28b53ef149b36be2885ef18e8276265481f24b6f7f71383
container_end_page 117
container_issue
container_start_page 106
container_title Carbon (New York)
container_volume 83
creator Mironov, B.E.
Freeman, H.M.
Brown, A.P.
Hage, F.S.
Scott, A.J.
Westwood, A.V.K.
Da Costa, J.-P.
Weisbecker, P.
Brydson, R.M.D.
description Structural and chemical bonding changes in nuclear graphite have been investigated during in-situ electron irradiation in a transmission electron microscope (TEM); electron beam irradiation has been employed as a surrogate for neutron irradiation of nuclear grade graphite in nuclear reactors. This paper aims to set out a methodology for analysing the microstructure of electron-irradiated graphite which can then be extended to the analysis of neutron-irradiated graphites. The damage produced by exposure to 200keV electrons was examined up to a total dose of approximately 0.5dpa (equivalent to an electron fluence of 5.6×1021electronscm−2). During electron exposure, high resolution TEM images and electron energy loss spectra (EELS) were acquired periodically in order to record changes in structural (dis)order and chemical bonding, by quantitatively analysing the variation in phase contrast images and EEL spectra.
doi_str_mv 10.1016/j.carbon.2014.11.019
format article
fullrecord <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_01120154v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0008622314010914</els_id><sourcerecordid>1685790912</sourcerecordid><originalsourceid>FETCH-LOGICAL-c485t-d170c2f7e22211d4ee28b53ef149b36be2885ef18e8276265481f24b6f7f71383</originalsourceid><addsrcrecordid>eNp9UbtOxDAQtBBIHI8_oHAJRYLXcRKnQUKIl3QSDdSW42zAp1wc7BzS8fU4Fx4dlT2j2VnNDiFnwFJgUFyuUqN97fqUMxApQMqg2iMLkGWWZLKCfbJgjMmk4Dw7JEchrCIUEsSCfN52aEbvemq9143Vo41_19J-YzrUnr56PbzZEWkYN43FhtZbOnrdh7UNYdLij8HaGu-CccOW6r7547FH_7qlnQuBhmFH7lQn5KDVXcDT7_eYvNzdPt88JMun-8eb62VihMzHpIGSGd6WyDkHaAQil3WeYQuiqrOijlDmEUmUvCx4kcdgLRd10ZZtCZnMjsnF7PumOzV4u9Z-q5y26uF6qSaOAcTD5eIDovZ81g7evW8wjCrGNNh1uke3CQoKmZcVq4BHqZilU-rgsf31BqamWtRKzbWoqRYFEBdVcexqHsMY-cOiV8FY7A021sfbqMbZ_w2-AEDJmek</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1685790912</pqid></control><display><type>article</type><title>Electron irradiation of nuclear graphite studied by transmission electron microscopy and electron energy loss spectroscopy</title><source>ScienceDirect Journals</source><creator>Mironov, B.E. ; Freeman, H.M. ; Brown, A.P. ; Hage, F.S. ; Scott, A.J. ; Westwood, A.V.K. ; Da Costa, J.-P. ; Weisbecker, P. ; Brydson, R.M.D.</creator><creatorcontrib>Mironov, B.E. ; Freeman, H.M. ; Brown, A.P. ; Hage, F.S. ; Scott, A.J. ; Westwood, A.V.K. ; Da Costa, J.-P. ; Weisbecker, P. ; Brydson, R.M.D.</creatorcontrib><description>Structural and chemical bonding changes in nuclear graphite have been investigated during in-situ electron irradiation in a transmission electron microscope (TEM); electron beam irradiation has been employed as a surrogate for neutron irradiation of nuclear grade graphite in nuclear reactors. This paper aims to set out a methodology for analysing the microstructure of electron-irradiated graphite which can then be extended to the analysis of neutron-irradiated graphites. The damage produced by exposure to 200keV electrons was examined up to a total dose of approximately 0.5dpa (equivalent to an electron fluence of 5.6×1021electronscm−2). During electron exposure, high resolution TEM images and electron energy loss spectra (EELS) were acquired periodically in order to record changes in structural (dis)order and chemical bonding, by quantitatively analysing the variation in phase contrast images and EEL spectra.</description><identifier>ISSN: 0008-6223</identifier><identifier>EISSN: 1873-3891</identifier><identifier>DOI: 10.1016/j.carbon.2014.11.019</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Chemical Sciences ; Computer Science ; Electron energy loss spectroscopy ; Electron irradiation ; Exposure ; Graphite ; Image acquisition ; Image contrast ; Material chemistry ; Signal and Image Processing ; Spectra ; Transmission electron microscopy</subject><ispartof>Carbon (New York), 2015-03, Vol.83, p.106-117</ispartof><rights>2014 Elsevier Ltd</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c485t-d170c2f7e22211d4ee28b53ef149b36be2885ef18e8276265481f24b6f7f71383</citedby><cites>FETCH-LOGICAL-c485t-d170c2f7e22211d4ee28b53ef149b36be2885ef18e8276265481f24b6f7f71383</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://hal.science/hal-01120154$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Mironov, B.E.</creatorcontrib><creatorcontrib>Freeman, H.M.</creatorcontrib><creatorcontrib>Brown, A.P.</creatorcontrib><creatorcontrib>Hage, F.S.</creatorcontrib><creatorcontrib>Scott, A.J.</creatorcontrib><creatorcontrib>Westwood, A.V.K.</creatorcontrib><creatorcontrib>Da Costa, J.-P.</creatorcontrib><creatorcontrib>Weisbecker, P.</creatorcontrib><creatorcontrib>Brydson, R.M.D.</creatorcontrib><title>Electron irradiation of nuclear graphite studied by transmission electron microscopy and electron energy loss spectroscopy</title><title>Carbon (New York)</title><description>Structural and chemical bonding changes in nuclear graphite have been investigated during in-situ electron irradiation in a transmission electron microscope (TEM); electron beam irradiation has been employed as a surrogate for neutron irradiation of nuclear grade graphite in nuclear reactors. This paper aims to set out a methodology for analysing the microstructure of electron-irradiated graphite which can then be extended to the analysis of neutron-irradiated graphites. The damage produced by exposure to 200keV electrons was examined up to a total dose of approximately 0.5dpa (equivalent to an electron fluence of 5.6×1021electronscm−2). During electron exposure, high resolution TEM images and electron energy loss spectra (EELS) were acquired periodically in order to record changes in structural (dis)order and chemical bonding, by quantitatively analysing the variation in phase contrast images and EEL spectra.</description><subject>Chemical Sciences</subject><subject>Computer Science</subject><subject>Electron energy loss spectroscopy</subject><subject>Electron irradiation</subject><subject>Exposure</subject><subject>Graphite</subject><subject>Image acquisition</subject><subject>Image contrast</subject><subject>Material chemistry</subject><subject>Signal and Image Processing</subject><subject>Spectra</subject><subject>Transmission electron microscopy</subject><issn>0008-6223</issn><issn>1873-3891</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9UbtOxDAQtBBIHI8_oHAJRYLXcRKnQUKIl3QSDdSW42zAp1wc7BzS8fU4Fx4dlT2j2VnNDiFnwFJgUFyuUqN97fqUMxApQMqg2iMLkGWWZLKCfbJgjMmk4Dw7JEchrCIUEsSCfN52aEbvemq9143Vo41_19J-YzrUnr56PbzZEWkYN43FhtZbOnrdh7UNYdLij8HaGu-CccOW6r7547FH_7qlnQuBhmFH7lQn5KDVXcDT7_eYvNzdPt88JMun-8eb62VihMzHpIGSGd6WyDkHaAQil3WeYQuiqrOijlDmEUmUvCx4kcdgLRd10ZZtCZnMjsnF7PumOzV4u9Z-q5y26uF6qSaOAcTD5eIDovZ81g7evW8wjCrGNNh1uke3CQoKmZcVq4BHqZilU-rgsf31BqamWtRKzbWoqRYFEBdVcexqHsMY-cOiV8FY7A021sfbqMbZ_w2-AEDJmek</recordid><startdate>201503</startdate><enddate>201503</enddate><creator>Mironov, B.E.</creator><creator>Freeman, H.M.</creator><creator>Brown, A.P.</creator><creator>Hage, F.S.</creator><creator>Scott, A.J.</creator><creator>Westwood, A.V.K.</creator><creator>Da Costa, J.-P.</creator><creator>Weisbecker, P.</creator><creator>Brydson, R.M.D.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>1XC</scope><scope>VOOES</scope></search><sort><creationdate>201503</creationdate><title>Electron irradiation of nuclear graphite studied by transmission electron microscopy and electron energy loss spectroscopy</title><author>Mironov, B.E. ; Freeman, H.M. ; Brown, A.P. ; Hage, F.S. ; Scott, A.J. ; Westwood, A.V.K. ; Da Costa, J.-P. ; Weisbecker, P. ; Brydson, R.M.D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c485t-d170c2f7e22211d4ee28b53ef149b36be2885ef18e8276265481f24b6f7f71383</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Chemical Sciences</topic><topic>Computer Science</topic><topic>Electron energy loss spectroscopy</topic><topic>Electron irradiation</topic><topic>Exposure</topic><topic>Graphite</topic><topic>Image acquisition</topic><topic>Image contrast</topic><topic>Material chemistry</topic><topic>Signal and Image Processing</topic><topic>Spectra</topic><topic>Transmission electron microscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mironov, B.E.</creatorcontrib><creatorcontrib>Freeman, H.M.</creatorcontrib><creatorcontrib>Brown, A.P.</creatorcontrib><creatorcontrib>Hage, F.S.</creatorcontrib><creatorcontrib>Scott, A.J.</creatorcontrib><creatorcontrib>Westwood, A.V.K.</creatorcontrib><creatorcontrib>Da Costa, J.-P.</creatorcontrib><creatorcontrib>Weisbecker, P.</creatorcontrib><creatorcontrib>Brydson, R.M.D.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical &amp; Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Carbon (New York)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mironov, B.E.</au><au>Freeman, H.M.</au><au>Brown, A.P.</au><au>Hage, F.S.</au><au>Scott, A.J.</au><au>Westwood, A.V.K.</au><au>Da Costa, J.-P.</au><au>Weisbecker, P.</au><au>Brydson, R.M.D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electron irradiation of nuclear graphite studied by transmission electron microscopy and electron energy loss spectroscopy</atitle><jtitle>Carbon (New York)</jtitle><date>2015-03</date><risdate>2015</risdate><volume>83</volume><spage>106</spage><epage>117</epage><pages>106-117</pages><issn>0008-6223</issn><eissn>1873-3891</eissn><abstract>Structural and chemical bonding changes in nuclear graphite have been investigated during in-situ electron irradiation in a transmission electron microscope (TEM); electron beam irradiation has been employed as a surrogate for neutron irradiation of nuclear grade graphite in nuclear reactors. This paper aims to set out a methodology for analysing the microstructure of electron-irradiated graphite which can then be extended to the analysis of neutron-irradiated graphites. The damage produced by exposure to 200keV electrons was examined up to a total dose of approximately 0.5dpa (equivalent to an electron fluence of 5.6×1021electronscm−2). During electron exposure, high resolution TEM images and electron energy loss spectra (EELS) were acquired periodically in order to record changes in structural (dis)order and chemical bonding, by quantitatively analysing the variation in phase contrast images and EEL spectra.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.carbon.2014.11.019</doi><tpages>12</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 0008-6223
ispartof Carbon (New York), 2015-03, Vol.83, p.106-117
issn 0008-6223
1873-3891
language eng
recordid cdi_hal_primary_oai_HAL_hal_01120154v1
source ScienceDirect Journals
subjects Chemical Sciences
Computer Science
Electron energy loss spectroscopy
Electron irradiation
Exposure
Graphite
Image acquisition
Image contrast
Material chemistry
Signal and Image Processing
Spectra
Transmission electron microscopy
title Electron irradiation of nuclear graphite studied by transmission electron microscopy and electron energy loss spectroscopy
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T09%3A35%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Electron%20irradiation%20of%20nuclear%20graphite%20studied%20by%20transmission%20electron%20microscopy%20and%20electron%20energy%20loss%20spectroscopy&rft.jtitle=Carbon%20(New%20York)&rft.au=Mironov,%20B.E.&rft.date=2015-03&rft.volume=83&rft.spage=106&rft.epage=117&rft.pages=106-117&rft.issn=0008-6223&rft.eissn=1873-3891&rft_id=info:doi/10.1016/j.carbon.2014.11.019&rft_dat=%3Cproquest_hal_p%3E1685790912%3C/proquest_hal_p%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c485t-d170c2f7e22211d4ee28b53ef149b36be2885ef18e8276265481f24b6f7f71383%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1685790912&rft_id=info:pmid/&rfr_iscdi=true