Loading…
Environmental ageing of aerospace epoxy adhesive in bonded assembly configuration
Aerospace epoxy adhesive has been subjected to various environmental ageing processes. A comparative study is performed between ageing under vacuum and atmospheric pressure for various ageing temperatures. The macroscopic behaviour of the assemblies is investigated by single lap shear test. Glass tr...
Saved in:
| Published in: | Journal of thermal analysis and calorimetry 2013-11, Vol.114 (2), p.621-628 |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c538t-d9ba06fbc926850d5e5340c80b57bc0c8bc983c59f6509f1bf035484467903ea3 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c538t-d9ba06fbc926850d5e5340c80b57bc0c8bc983c59f6509f1bf035484467903ea3 |
| container_end_page | 628 |
| container_issue | 2 |
| container_start_page | 621 |
| container_title | Journal of thermal analysis and calorimetry |
| container_volume | 114 |
| creator | Causse, Nicolas Dantras, Eric Tonon, Claire Chevalier, Mathieu Combes, Hélène Guigue, Pascale Lacabanne, Colette |
| description | Aerospace epoxy adhesive has been subjected to various environmental ageing processes. A comparative study is performed between ageing under vacuum and atmospheric pressure for various ageing temperatures. The macroscopic behaviour of the assemblies is investigated by single lap shear test. Glass transition temperature of the bulk adhesive is followed by differential scanning calorimetry. Molecular mobility of the adhesive in service configuration is studied by dynamic dielectric spectroscopy. No significant difference is noticed due to an ageing under vacuum. A comparison between test results after each isotherm ageing highlights the temperature influence. For ageing of adhesive in a vitreous state, the crosslink density increases. For ageing of adhesive in a rubbery state, a severe decrease of glass transition is observed. The influence of additives and physical ageing is null. This plasticisation effect might be associated with the homogenisation of the structure of epoxy due to the molecular mobility of loose chains. |
| doi_str_mv | 10.1007/s10973-013-3009-3 |
| format | article |
| fullrecord | <record><control><sourceid>gale_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_01136617v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A348873405</galeid><sourcerecordid>A348873405</sourcerecordid><originalsourceid>FETCH-LOGICAL-c538t-d9ba06fbc926850d5e5340c80b57bc0c8bc983c59f6509f1bf035484467903ea3</originalsourceid><addsrcrecordid>eNp9kU1r3DAQhk1poSHND-jNl0J7cDqyLFk-LiFtAguhX2cxlkeOii1tJe-S_ffV4iWll6CDhplnhnfmLYr3DK4ZQPs5MehaXgHjFQfoKv6quGBCqaruavk6xzzHkgl4W1yl5HqoGchOqO6i-HbrDy4GP5NfcCpxJOfHMtgSKYa0Q0Ml7cLTscThkZI7UOl82Qc_0FBiSjT307E0wVs37iMuLvh3xRuLU6Kr839Z_Ppy-_Pmrto-fL2_2WwrI7haqqHrEaTtTZaoBAyCBG_AKOhF25sc5IriRnRWCugs6y1w0aimkW0HnJBfFp_WuY846V10M8ajDuj03WarTzlgjEvJ2gPL7MeV3cXwZ09p0bNLhqYJPYV90vk0soFa1l1Gr1d0xIm08zYsEU1-A80uL0rW5fyGN0q1WbD4p-PckJmFnpYR9ynp-x_f_2fZypp83BTJPgtnoE9W6tXKrJ3rk5Wa554PZ-2YDE42ojcuPTfWrWJMNjJz9cqlXPIjRf077KPPFrww_C-jIKvM</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1506402629</pqid></control><display><type>article</type><title>Environmental ageing of aerospace epoxy adhesive in bonded assembly configuration</title><source>Springer Nature</source><creator>Causse, Nicolas ; Dantras, Eric ; Tonon, Claire ; Chevalier, Mathieu ; Combes, Hélène ; Guigue, Pascale ; Lacabanne, Colette</creator><creatorcontrib>Causse, Nicolas ; Dantras, Eric ; Tonon, Claire ; Chevalier, Mathieu ; Combes, Hélène ; Guigue, Pascale ; Lacabanne, Colette</creatorcontrib><description>Aerospace epoxy adhesive has been subjected to various environmental ageing processes. A comparative study is performed between ageing under vacuum and atmospheric pressure for various ageing temperatures. The macroscopic behaviour of the assemblies is investigated by single lap shear test. Glass transition temperature of the bulk adhesive is followed by differential scanning calorimetry. Molecular mobility of the adhesive in service configuration is studied by dynamic dielectric spectroscopy. No significant difference is noticed due to an ageing under vacuum. A comparison between test results after each isotherm ageing highlights the temperature influence. For ageing of adhesive in a vitreous state, the crosslink density increases. For ageing of adhesive in a rubbery state, a severe decrease of glass transition is observed. The influence of additives and physical ageing is null. This plasticisation effect might be associated with the homogenisation of the structure of epoxy due to the molecular mobility of loose chains.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>EISSN: 1572-8943</identifier><identifier>DOI: 10.1007/s10973-013-3009-3</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Adhesive bonding ; Adhesives ; Adhesives and sealants industry ; Ageing ; Analytical Chemistry ; Applied sciences ; Calorimetry ; Chemical Sciences ; Chemistry ; Chemistry and Materials Science ; Epoxy resins ; Exact sciences and technology ; Inorganic Chemistry ; Measurement Science and Instrumentation ; Physical Chemistry ; Physical properties ; Polymer industry, paints, wood ; Polymer Sciences ; Polymers ; Properties and testing ; Technology of polymers</subject><ispartof>Journal of thermal analysis and calorimetry, 2013-11, Vol.114 (2), p.621-628</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2013</rights><rights>2015 INIST-CNRS</rights><rights>COPYRIGHT 2013 Springer</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c538t-d9ba06fbc926850d5e5340c80b57bc0c8bc983c59f6509f1bf035484467903ea3</citedby><cites>FETCH-LOGICAL-c538t-d9ba06fbc926850d5e5340c80b57bc0c8bc983c59f6509f1bf035484467903ea3</cites><orcidid>0000-0002-0111-3184 ; 0000-0002-5601-2217</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27811646$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-01136617$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Causse, Nicolas</creatorcontrib><creatorcontrib>Dantras, Eric</creatorcontrib><creatorcontrib>Tonon, Claire</creatorcontrib><creatorcontrib>Chevalier, Mathieu</creatorcontrib><creatorcontrib>Combes, Hélène</creatorcontrib><creatorcontrib>Guigue, Pascale</creatorcontrib><creatorcontrib>Lacabanne, Colette</creatorcontrib><title>Environmental ageing of aerospace epoxy adhesive in bonded assembly configuration</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>Aerospace epoxy adhesive has been subjected to various environmental ageing processes. A comparative study is performed between ageing under vacuum and atmospheric pressure for various ageing temperatures. The macroscopic behaviour of the assemblies is investigated by single lap shear test. Glass transition temperature of the bulk adhesive is followed by differential scanning calorimetry. Molecular mobility of the adhesive in service configuration is studied by dynamic dielectric spectroscopy. No significant difference is noticed due to an ageing under vacuum. A comparison between test results after each isotherm ageing highlights the temperature influence. For ageing of adhesive in a vitreous state, the crosslink density increases. For ageing of adhesive in a rubbery state, a severe decrease of glass transition is observed. The influence of additives and physical ageing is null. This plasticisation effect might be associated with the homogenisation of the structure of epoxy due to the molecular mobility of loose chains.</description><subject>Adhesive bonding</subject><subject>Adhesives</subject><subject>Adhesives and sealants industry</subject><subject>Ageing</subject><subject>Analytical Chemistry</subject><subject>Applied sciences</subject><subject>Calorimetry</subject><subject>Chemical Sciences</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Epoxy resins</subject><subject>Exact sciences and technology</subject><subject>Inorganic Chemistry</subject><subject>Measurement Science and Instrumentation</subject><subject>Physical Chemistry</subject><subject>Physical properties</subject><subject>Polymer industry, paints, wood</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Properties and testing</subject><subject>Technology of polymers</subject><issn>1388-6150</issn><issn>1588-2926</issn><issn>1572-8943</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kU1r3DAQhk1poSHND-jNl0J7cDqyLFk-LiFtAguhX2cxlkeOii1tJe-S_ffV4iWll6CDhplnhnfmLYr3DK4ZQPs5MehaXgHjFQfoKv6quGBCqaruavk6xzzHkgl4W1yl5HqoGchOqO6i-HbrDy4GP5NfcCpxJOfHMtgSKYa0Q0Ml7cLTscThkZI7UOl82Qc_0FBiSjT307E0wVs37iMuLvh3xRuLU6Kr839Z_Ppy-_Pmrto-fL2_2WwrI7haqqHrEaTtTZaoBAyCBG_AKOhF25sc5IriRnRWCugs6y1w0aimkW0HnJBfFp_WuY846V10M8ajDuj03WarTzlgjEvJ2gPL7MeV3cXwZ09p0bNLhqYJPYV90vk0soFa1l1Gr1d0xIm08zYsEU1-A80uL0rW5fyGN0q1WbD4p-PckJmFnpYR9ynp-x_f_2fZypp83BTJPgtnoE9W6tXKrJ3rk5Wa554PZ-2YDE42ojcuPTfWrWJMNjJz9cqlXPIjRf077KPPFrww_C-jIKvM</recordid><startdate>20131101</startdate><enddate>20131101</enddate><creator>Causse, Nicolas</creator><creator>Dantras, Eric</creator><creator>Tonon, Claire</creator><creator>Chevalier, Mathieu</creator><creator>Combes, Hélène</creator><creator>Guigue, Pascale</creator><creator>Lacabanne, Colette</creator><general>Springer Netherlands</general><general>Springer</general><general>Springer Verlag</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>H8D</scope><scope>JG9</scope><scope>L7M</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-0111-3184</orcidid><orcidid>https://orcid.org/0000-0002-5601-2217</orcidid></search><sort><creationdate>20131101</creationdate><title>Environmental ageing of aerospace epoxy adhesive in bonded assembly configuration</title><author>Causse, Nicolas ; Dantras, Eric ; Tonon, Claire ; Chevalier, Mathieu ; Combes, Hélène ; Guigue, Pascale ; Lacabanne, Colette</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c538t-d9ba06fbc926850d5e5340c80b57bc0c8bc983c59f6509f1bf035484467903ea3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Adhesive bonding</topic><topic>Adhesives</topic><topic>Adhesives and sealants industry</topic><topic>Ageing</topic><topic>Analytical Chemistry</topic><topic>Applied sciences</topic><topic>Calorimetry</topic><topic>Chemical Sciences</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Epoxy resins</topic><topic>Exact sciences and technology</topic><topic>Inorganic Chemistry</topic><topic>Measurement Science and Instrumentation</topic><topic>Physical Chemistry</topic><topic>Physical properties</topic><topic>Polymer industry, paints, wood</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Properties and testing</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Causse, Nicolas</creatorcontrib><creatorcontrib>Dantras, Eric</creatorcontrib><creatorcontrib>Tonon, Claire</creatorcontrib><creatorcontrib>Chevalier, Mathieu</creatorcontrib><creatorcontrib>Combes, Hélène</creatorcontrib><creatorcontrib>Guigue, Pascale</creatorcontrib><creatorcontrib>Lacabanne, Colette</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Gale In Context: Science</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Causse, Nicolas</au><au>Dantras, Eric</au><au>Tonon, Claire</au><au>Chevalier, Mathieu</au><au>Combes, Hélène</au><au>Guigue, Pascale</au><au>Lacabanne, Colette</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Environmental ageing of aerospace epoxy adhesive in bonded assembly configuration</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2013-11-01</date><risdate>2013</risdate><volume>114</volume><issue>2</issue><spage>621</spage><epage>628</epage><pages>621-628</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><eissn>1572-8943</eissn><abstract>Aerospace epoxy adhesive has been subjected to various environmental ageing processes. A comparative study is performed between ageing under vacuum and atmospheric pressure for various ageing temperatures. The macroscopic behaviour of the assemblies is investigated by single lap shear test. Glass transition temperature of the bulk adhesive is followed by differential scanning calorimetry. Molecular mobility of the adhesive in service configuration is studied by dynamic dielectric spectroscopy. No significant difference is noticed due to an ageing under vacuum. A comparison between test results after each isotherm ageing highlights the temperature influence. For ageing of adhesive in a vitreous state, the crosslink density increases. For ageing of adhesive in a rubbery state, a severe decrease of glass transition is observed. The influence of additives and physical ageing is null. This plasticisation effect might be associated with the homogenisation of the structure of epoxy due to the molecular mobility of loose chains.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10973-013-3009-3</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-0111-3184</orcidid><orcidid>https://orcid.org/0000-0002-5601-2217</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1388-6150 |
| ispartof | Journal of thermal analysis and calorimetry, 2013-11, Vol.114 (2), p.621-628 |
| issn | 1388-6150 1588-2926 1572-8943 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_01136617v1 |
| source | Springer Nature |
| subjects | Adhesive bonding Adhesives Adhesives and sealants industry Ageing Analytical Chemistry Applied sciences Calorimetry Chemical Sciences Chemistry Chemistry and Materials Science Epoxy resins Exact sciences and technology Inorganic Chemistry Measurement Science and Instrumentation Physical Chemistry Physical properties Polymer industry, paints, wood Polymer Sciences Polymers Properties and testing Technology of polymers |
| title | Environmental ageing of aerospace epoxy adhesive in bonded assembly configuration |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-02T14%3A17%3A50IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-gale_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Environmental%20ageing%20of%20aerospace%20epoxy%20adhesive%20in%20bonded%20assembly%20configuration&rft.jtitle=Journal%20of%20thermal%20analysis%20and%20calorimetry&rft.au=Causse,%20Nicolas&rft.date=2013-11-01&rft.volume=114&rft.issue=2&rft.spage=621&rft.epage=628&rft.pages=621-628&rft.issn=1388-6150&rft.eissn=1588-2926&rft_id=info:doi/10.1007/s10973-013-3009-3&rft_dat=%3Cgale_hal_p%3EA348873405%3C/gale_hal_p%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c538t-d9ba06fbc926850d5e5340c80b57bc0c8bc983c59f6509f1bf035484467903ea3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1506402629&rft_id=info:pmid/&rft_galeid=A348873405&rfr_iscdi=true |