Electronic vs. structural ordering in a manganese(III) spin crossover complex

A symmetry breaking spin transition in a Mn(III) complex is reported with three structural phases, a high symmetry high temperature S = 2 phase, an intermediate S = 1/S = 2 ordered phase and an aperiodic low temperature phase with S = 1 cations. The aperiodicity is interpreted as resulting from long...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (99), p.17540-17543
Main Authors: Fitzpatrick, Anthony J, Trzop, Elzbieta, Trzop, Eliza, Müller-Bunz, Helge, Dîrtu, Marinela M, Garcia, Yann, Collet, Eric, Morgan, Grace G
Format: Article
Language:English
Subjects:
Condensed Matter
Materials Science
Physics
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Summary:A symmetry breaking spin transition in a Mn(III) complex is reported with three structural phases, a high symmetry high temperature S = 2 phase, an intermediate S = 1/S = 2 ordered phase and an aperiodic low temperature phase with S = 1 cations. The aperiodicity is interpreted as resulting from long-range ordering of the NTf2(-) anions.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc05129k