Influence of UV grafting conditions and gel formation on the loading and stabilization of palladium nanoparticles in photografted polyethersulfone membrane for catalytic reactions

• Published in: Journal of membrane science 2014-04, Vol.455, p.55-63
• Main Authors: Emin, Clélia, Remigy, Jean-Christophe, Lahitte, Jean-François
• Format: Article
• Language: English
• Subjects: Applied sciences; Catalysis; Catalysts; Catalytic membrane reactor; Chemical engineering; Chemical Sciences; Chemistry; Colloidal state and disperse state; Exact sciences and technology; Exchange resins and membranes; Fibers; Forms of application and semi-finished materials; Functionalization; General and physical chemistry; Grafting; Hollow fiber membrane; Membranes; Nanoparticles; Palladium nanoparticles; Physical and chemical studies. Granulometry. Electrokinetic phenomena; Polyethersulfones; Polymer industry, paints, wood; Reactors; Technology of polymers; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; UV photografting
• ISSN: 0376-7388; 1873-3123
• DOI: 10.1016/j.memsci.2013.12.049

This paper reports innovative coupling for the development of catalytic membrane reactors. Photografting for the modification of membrane surfaces has been extensively studied and we used the results to optimize metal nanoparticle loading. Polyethersulfone hollow fibers were modified by poly(acrylic acid) grafting and the impact of a cross-linked network and a polymer gel grafted layer on metal loading was examined. Transmission electron microscopy images showed well dispersed metal nanoparticles close to the surface. The catalytic activity of the different hollow fibers was assessed by the reduction of p-nitrophenol into p-aminophenol and a conversion yield of close to 100% was found. We demonstrated the possibility of obtaining various reactors by varying the residence time through alteration of the grafted layer. •Polymeric catalytic membranes loaded with Pd nanoparticles.•Nanoparticles stabilized by polyelectrolytes photografted at the membrane surface.•Influence of grafted layer morphology in Pd loading.•Good catalytic activity for the reduction of p-nitrophenol.