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Laser printing of azo-derivative thin films for non-linear optical applications

•1-phenyl-3-methyl-4-(1′-azo-2′-sodium carboxylate)-pyrazole-5-one films are grown.•Laser-based processing techniques are presented and discussed.•The influence of a metallic dynamic release layer during LIFT is emphasized.•The structure, morphology and optical properties of the films/pixels are dis...

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Bibliographic Details
Published in:Applied surface science 2015-05, Vol.336, p.200-205
Main Authors: Matei, Andreea, Constantinescu, Catalin, Mitu, Bogdana, Filipescu, Mihaela, Ion, Valentin, Ionita, Iulian, Brajnicov, Simona, Alloncle, Anne-Patricia, Delaporte, Philippe, Emandi, Ana, Dinescu, Maria
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Language:English
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Summary:•1-phenyl-3-methyl-4-(1′-azo-2′-sodium carboxylate)-pyrazole-5-one films are grown.•Laser-based processing techniques are presented and discussed.•The influence of a metallic dynamic release layer during LIFT is emphasized.•The structure, morphology and optical properties of the films/pixels are discussed. The use of laser-based processing is presented here for the transfer of azo-derivatives, for optoelectronics assembly applications. Laser-printing techniques are also adequate tools for rapid prototyping of diverse materials, since they avoid the usage of solutions, moulds, lithography masks, etc. Here, we present a study on the laser-induced forward transfer (LIFT) and printing of micrometric-sized pixels (350μm×350μm), by using matrix-assisted pulsed laser evaporation (MAPLE) deposited thin film donors. Due to their particular optical properties, i.e. second harmonic generation, optical limiting and all-optical poling, and with applications in optoelectronics and sensor development, azo-dyes have been intensively studied in bulk or as thin films. The influence of a metallic dynamic release layer (DRL) during LIFT is investigated.
ISSN:0169-4332
1873-5584
DOI:10.1016/j.apsusc.2014.11.022