Hydrogen production by hydrothermal oxidation of FeO under acidic conditions

• Published in: International journal of hydrogen energy 2017-01, Vol.42 (2), p.795-806
• Main Authors: Crouzet, C., Brunet, F., Recham, N., Findling, N., Lanson, M., Guyot, F., Ferrasse, J.-H., Goffé, B.
• Format: Article
• Language: English
• Subjects: Acetic acid; Chemical and Process Engineering; Chemical engineering; Chemical Sciences; Engineering Sciences; FeO oxidation; Hydrogen production; Hydrothermal conditions; Steel slags
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2016.10.019

The production of H2 by oxidation of FeO, taken here as model compound for steel slags, has been investigated both in pure water and under acidic aqueous conditions in the 373–573 K temperature range. Whereas after 65 h, H2 yield was negligible in pure water at 423 K, the reaction 3 FeO(s) + H2O(l) → Fe3O4(s) + H2(aq) reached near completion at the same temperature within 10 h in a solution containing 0.05 mol/l acetic acid. Increasing acetic acid concentration by one order of magnitude did not yield significantly more H2. At identical initial pH, acetic acid was found to be more efficient than oxalic acid and hydrochloric acid at enhancing H2 production. Acidic conditions increased FeO dissolution kinetics and, consequently, improved H2 yield. The specific efficiency of acetic acid resides in its thermal stability as well as in the potential of ligand-promoted Fe(II) dissolution. We show that the positive kinetics effect of mild acetic acid solutions over H2 yield evidenced on FeO does not apply directly to steel slags which buffer the pH to high values due to the presence of large amounts of CaO. •Hydrogen production from the FeO – H2O redox system.•Kinetic study performed under hydrothermal conditions.•Influence of pH and ligand-promoted dissolution on FeO oxidation kinetic.•Identified efficiency of dilute acetic acid.•Extrapolation to CaO–FeO mixes, steel slag equivalent system.