An unprecedented trinuclear FeII triazole-based complex exhibiting a concerted and complete sharp spin transition above room temperature

We report a triazole-based trinuclear complex as the first example that displays a complete one-step first-order [HS-HS-HS] ↔ [LS-LS-LS] spin transition at 318 K. The strong ferro-elastic interactions, between the three metal centers, have been identified as the source of the concerted spin transiti...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2017-07, Vol.53 (59), p.8356-8359
Main Authors: Pittala, Narsimhulu, Thétiot, Franck, Charles, Catherine, Triki, Smail, Boukheddaden, Kamel, Chastanet, Guillaume, Marchivie, Mathieu
Format: Article
Language:English
Subjects:
Chemical Sciences
Cristallography
Inorganic chemistry
Material chemistry
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:We report a triazole-based trinuclear complex as the first example that displays a complete one-step first-order [HS-HS-HS] ↔ [LS-LS-LS] spin transition at 318 K. The strong ferro-elastic interactions, between the three metal centers, have been identified as the source of the concerted spin transition in this trinuclear complex.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc04112h