Combining Fourier Transform-Ion Cyclotron Resonance/Mass Spectrometry Analysis and Kendrick Plots for Silicon Speciation and Molecular Characterization in Petroleum Products at Trace Levels

A new method combining FT-ICR/MS analysis and Kendrick plots for the characterization of silicon species at trace levels in light petroleum products is presented. The method provides efficient instrumental detection limits ranging from 80 ng/kg to 5 μg/kg and reliable mass accuracy lower than 0.50 p...

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Published in:Analytical chemistry (Washington) 2012-05, Vol.84 (9), p.3998-4005
Main Authors: Chainet, Fabien, Ponthus, Jérémie, Lienemann, Charles-Philippe, Courtiade, Marion, Donard, Olivier François Xavier
Format: Article
Language:English
Subjects:
Analytical chemistry
Chemical Sciences
Chemistry
Exact sciences and technology
Fourier transforms
Mass spectrometry
Molecules
Petroleum products
Silicon
Spectrometric and optical methods
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cited_by cdi_FETCH-LOGICAL-a407t-19381d47db8f59ca75b3daf9ec5d68e118b2c3dba36692fd19abe87c4df671cd3
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description A new method combining FT-ICR/MS analysis and Kendrick plots for the characterization of silicon species at trace levels in light petroleum products is presented. The method provides efficient instrumental detection limits ranging from 80 ng/kg to 5 μg/kg and reliable mass accuracy lower than 0.50 ppm for model silicon molecules in spiked gasoline. More than 3000 peaks could be detected in the m/z 50–500 range depending on the nature of the gasoline sample analyzed. An in-house software program was used to calculate Kendrick plots. Then, an algorithm searched, selected, and represented silicon species classes (O2Si, O3Si, and O4Si classes) in Kendrick plots by incorporating model molecules' information (i.e., exact mass and intensity). This procedure allowed the complete characterization of more than 50 new silicon species with different degrees of unsaturation in petroleum products.
doi_str_mv 10.1021/ac202931s
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Analytical chemistry
Chemical Sciences
Chemistry
Exact sciences and technology
Fourier transforms
Mass spectrometry
Molecules
Petroleum products
Silicon
Spectrometric and optical methods
title Combining Fourier Transform-Ion Cyclotron Resonance/Mass Spectrometry Analysis and Kendrick Plots for Silicon Speciation and Molecular Characterization in Petroleum Products at Trace Levels
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