Stable (Aryl)(phosphino)carbenes:  New Ligands for Transition Metals

The first direct complexation of a stable phosphino carbene to a transition metal center is described. Both η- and η-coordination modes have been characterized spectroscopically. The Fischer-type structure of the η1-carbene rhodium complex was revealed by an X-ray diffraction study.

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Bibliographic Details
Published in:Journal of the American Chemical Society 2002-10, Vol.124 (40), p.11834-11835
Main Authors: Despagnet, Emmanuelle, Miqueu, Karinne, Gornitzka, Heinz, Dyer, Philip W, Bourissou, Didier, Bertrand, Guy
Format: Article
Language:English
Subjects:
Catalysis
Chemical Sciences
Coordination chemistry
or physical chemistry
Organic chemistry
Polymers
Theoretical and
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Description
Summary:The first direct complexation of a stable phosphino carbene to a transition metal center is described. Both η- and η-coordination modes have been characterized spectroscopically. The Fischer-type structure of the η1-carbene rhodium complex was revealed by an X-ray diffraction study.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja027201i