Sweep gas membrane distillation in a membrane contactor with metallic hollow-fibers

• Published in: Journal of membrane science 2015-11, Vol.493, p.167-178
• Main Authors: Shukla, S., Benes, N.E., Vankelecom, I., Méricq, J.P., Belleville, M.P., Hengl, N., Marcano, J. Sanchez
• Format: Article
• Language: English
• Subjects: Chemical Sciences; Hollow fibers; Metallic membranes; Sucrose solutions; Surface modification by PDMS; Sweep gas membrane distillation
• ISSN: 0376-7388; 1873-3123
• DOI: 10.1016/j.memsci.2015.06.040

This work revolves around the use of porous metal hollow fibers in membrane distillation. Various stages are covered, starting from membrane synthesis up to the testing of a pilot scale membrane module. Mechanically stable metal hollow fibers have been synthesized by phase inversion of a stainless steel particle loaded polymer solution, followed by thermal treatment to remove the polymer and sinter the particles together. The pore surface of the metal fibers has been made hydrophobic by functionalization with polydimethylsiloxane or stearic acid. A water evaporation flux of 0.2kgh−1m−2 was obtained at a feed water temperature of 333K and a sweep gas flow rate of 135Lh−1 (Reair=2458) with pure water as feed. Under similar operating conditions, an evaporation flux of 0.14kgh−1m−2 was achieved when a 600gL−1 sucrose solution was used as feed. [Display omitted] •Stainless-steel macroporous hollow fibers were prepared by combined phase inversion-sintering.•Polydimethylsiloxane coated hollow fibers exhibited long term stability and performance.•Sweep gas membrane distillation in countercurrent configuration with a 25 fibers module.•Water evaporation increased with increasing feed temperature and sweep gas flow.•Polarization phenomena reduced the water flux across membrane with increasing sucrose concentration.