Drastic solid-state luminescence color tuning of an archetypal Ir( iii ) complex using polyoxometalates and its application as a vapoluminescence chemosensor

Using a straightforward one-step synthetic procedure, the solid-state phosphorescence of the archetypal [Ir III (ppy) 2 (bpy)] + complex has been successfully tuned from green to yellow, orange and red by its association with a series of polyoxometalates. Such new materials can exhibit remarkable va...

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Bibliographic Details
Published in:Journal of materials chemistry. C, Materials for optical and electronic devices Materials for optical and electronic devices, 2016-01, Vol.4 (48), p.11392-11395
Main Authors: Bolle, P., Serier-Brault, H., Génois, R., Faulques, E., Boulmier, A., Oms, O., Lepeltier, M., Marrot, J., Dolbecq, A., Mialane, P., Dessapt, R.
Format: Article
Language:English
Subjects:
Chemoreceptors
Color
Condensed Matter
Conversion
Luminescence
Materials Science
Organic compounds
Physics
Polyoxometallates
Tuning
Volatile organic compounds
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Summary:Using a straightforward one-step synthetic procedure, the solid-state phosphorescence of the archetypal [Ir III (ppy) 2 (bpy)] + complex has been successfully tuned from green to yellow, orange and red by its association with a series of polyoxometalates. Such new materials can exhibit remarkable vapoluminescence properties for the detection of volatile organic compounds (VOCs) even in the presence of moisture via a new polymorphous conversion mechanism.
ISSN:2050-7526
2050-7534
DOI:10.1039/C6TC04341K