Facilitated transport of copper(II) across supported liquid membrane and polymeric plasticized membrane containing 3-phenyl-4-benzoylisoxazol-5-one as carrier

The potential of 3-phenyl-4-benzoylisoxazol-5-one (HPBI) as metal extractant has been evaluated for the first time for Cu(II) transport from aqueous nitrate solutions by supported liquid membrane (SLM) in the solvents chloroform, 2-nitro phenyl octyl ether (NPOE) and dodecyl nitro phenyl ether (DNPE...

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Bibliographic Details
Published in:Journal of membrane science 2008-12, Vol.325 (2), p.605-611
Main Authors: Mitiche, L., Tingry, S., Seta, P., Sahmoune, A.
Format: Article
Language:English
Subjects:
3-Phenyl-4-benzoylisoxazol-5-one (HPBI)
Chemical Sciences
Copper
Facilitated transport
Plasticized polymeric membrane
Supported liquid membrane
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Summary:The potential of 3-phenyl-4-benzoylisoxazol-5-one (HPBI) as metal extractant has been evaluated for the first time for Cu(II) transport from aqueous nitrate solutions by supported liquid membrane (SLM) in the solvents chloroform, 2-nitro phenyl octyl ether (NPOE) and dodecyl nitro phenyl ether (DNPE). The efficiency of the membrane transport was optimized as a function of pH, temperature, aqueous phases and membrane composition. It follows the sequence CHCl 3 > DNPE > NPOE. The results suggested that the transport mechanism was mainly controlled by the diffusion of the Cu(PBI) 2 complex in the membrane core. A comparative investigation of Cu(II) transport ions has been made between SLM and polymeric plasticized membrane (PPM), containing HPBI with NPOE and DNPE as organic solvents or plasticizers in order to evaluate the feasibility of PPM with HPBI.
ISSN:0376-7388
1873-3123
DOI:10.1016/j.memsci.2008.08.021