Preparation of a new ceramic microfiltration membrane from mineral coal fly ash: Application to the treatment of the textile dying effluents

• Published in: Powder technology 2011-03, Vol.208 (2), p.427-432
• Main Authors: Jedidi, Ilyes, Khemakhem, Sabeur, Saïdi, Sami, Larbot, André, Elloumi-Ammar, Najoua, Fourati, Amine, Charfi, Aboulhassen, Salah, Abdelhamid Ben, Amar, Raja Ben
• Format: Article
• Language: English
• Subjects: Applied sciences; Ceramic microfiltration membrane; Ceramics; Chemical engineering; Chemical Sciences; Coal; Coal mines; Dying effluents; Exact sciences and technology; General purification processes; Macroporous support; Membrane separation (reverse osmosis, dialysis...); Membranes; Microfiltration; Mineral coal fly ash; Minerals; Miscellaneous; Paste extrusion process; Pollution; Porosity; Sintering, pelletization, granulation; Slip-casting process; Solid-solid systems; Textiles; Wastewaters; Water treatment and pollution
• ISSN: 0032-5910; 1873-328X
• DOI: 10.1016/j.powtec.2010.08.039

New microfiltration membranes from mineral coal fly-ash material are obtained using ceramic method. Paste from mineral coal fly ash (obtained by calcinations at 800 °C of non-grinded mineral coal) is extruded to elaborate a porous tubular configuration used as supports. The support heated at 1125 °C, shows an average pore diameter and porosity of about 4.5 μm and 51%, respectively. The properties in terms of mechanical and corrosion resistances are very interesting. The elaboration of the layer based on fly-ash powder (obtained by sintering at 700 °C of a finely grinded mineral coal) is performed by slip-casting method. The heating treatment at 800 °C leads to an average pore size of 0.25 μm. The water permeability determined of this membrane is 475 L/h m 2 bar. This membrane can be used for crossflow microfiltration. The application to the treatment of the dying effluents generated by the washing baths in the textile industry shows an important decrease of turbidity (inferior to 1 NTU), of chemical oxygen demand (COD) values (retention rate of about 75%) and a total color removal. The performances in term of permeate flux and efficiency were determined and compared to those obtained using a commercial alumina microfiltration membrane. Almost the same stabilised permeate flux was obtained (about 100 L h −1 m −2). So, it seems that the prepared membrane is suitable for such wastewater treatment. New microfiltration membranes from mineral coal fly-ash material are obtained using ceramic method. The support heated at 1125 °C, shows an average pore diameter and porosity of about 4.5 μm and 51%, respectively. The elaboration of the layer based on fly-ash powder is performed by slip-casting method. Sintering at 800 °C led to an average pore size of 0.25 μm. The water permeability determined of this membrane is 475 L/h m 2 bar. This membrane was applied to the filtration of the dying effluents generated by the washing baths in the textile industry and showed interesting results. [Display omitted]