Highly dispersed copper (oxide) nanoparticles prepared on SBA-15 partially occluded with the P123 surfactant: toward the design of active hydrogenation catalysts

• Published in: Catalysis science & technology 2017, Vol.7 (22), p.5376-5385
• Main Authors: Dragoi, B, Mazilu, I, Chirieac, A, Ciotonea, C, Ungureanu, A, Marceau, E, Dumitriu, E, Royer, S
• Format: Article
• Language: English
• Subjects: Catalysis; Catalysts; Chemical Sciences; Cinnamaldehyde; Confining; Copper oxides; Hydrogenation; Inorganic chemistry; Material chemistry; Moisture content; Nanoparticles; Porosity; Silicon dioxide; Supports
• ISSN: 2044-4753; 2044-4761
• DOI: 10.1039/c7cy01015j

Copper (oxide) nanoparticles with dispersion and size ranging from highly dispersed nanoparticles confined within the intra-wall pores to nanoparticles confined within the main mesopores can be simply produced via incipient wetness impregnation by using mesoporous silica supports containing the structure directing agent P123 partially occluding the intra-wall pores of SBA-15. Remarkably high copper dispersions of 69.5 down to 25.9% for metal loadings from 5 to 20 wt% were achieved as a result of the dual effect of the presence of surface silanol groups and the unique confining space between the silica walls and residual P123 in the intra-wall pores. The copper catalysts demonstrated outstanding activities in the hydrogenation of cinnamaldehyde, with TOF values ranging from 5.1 × 10 −3 to 22.1 × 10 −3 s −1 , which are much higher than those of other supported copper catalysts reported elsewhere and prepared using conventional approaches. Mesoporous SBA-15 silica containing intra-wall embedded polymeric P123 surfactant and presenting a high density of surface silanol groups effectively stabilizes copper phases.