Fluoride-assisted trifluoromethylation of aromatic thiones with (trifluoromethyl)trimethylsilane

Graphic In the presence of a stoichiometric amount of Bu 4NF·3H 2O, (trifluoromethyl)trimethylsilane reacts with aromatic thiones in both thiophilic and carbophilic ways to deliver, in medium yield, a mixture of (trifluoromethylthio)diarylmethane and 1,1-diaryl-2,2,2-trifluoroethanethiol, the former...

Full description

Saved in:
Bibliographic Details
Published in:Journal of fluorine chemistry 2003-12, Vol.124 (2), p.147-149
Main Authors: Large-Radix, Sylvie, Billard, Thierry, Langlois, Bernard R
Format: Article
Language:English
Subjects:
(Trifluoromethyl)trimethylsilane
Chemical Sciences
Organic chemistry
Trifluoromethyl sulfides
Trifluoromethylation
α-(Trifluoromethyl)thiols
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Graphic In the presence of a stoichiometric amount of Bu 4NF·3H 2O, (trifluoromethyl)trimethylsilane reacts with aromatic thiones in both thiophilic and carbophilic ways to deliver, in medium yield, a mixture of (trifluoromethylthio)diarylmethane and 1,1-diaryl-2,2,2-trifluoroethanethiol, the former product being the major one.
ISSN:0022-1139
1873-3328
DOI:10.1016/S0022-1139(03)00203-3