A [Fe III (Tp)(CN) 3 ] - scorpionate-based complex as a building block for designing ion storage hosts (Tp: hydrotrispyrazolylborate)

Using a scorpionate-based complex, [FeIII(Tp)(CN)3]-, as a building block, a new cyanide-based molecular material [{FeIII(Tp)(CN)3}2NiII(H2O)2]·4H2O (1), which can be viewed as a lower dimensional model of Prussian blue analogues, was investigated as a lithium-ion storage host.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (41), p.5189-5192
Main Authors: Jiménez, Juan-Ramón, Sugahara, Akira, Okubo, Masashi, Yamada, Atsuo, Chamoreau, Lise-Marie, Lisnard, Laurent, Lescouëzec, Rodrigue
Format: Article
Language:English
Subjects:
Chemical Sciences
Coordination chemistry
Ion storage
Lithium ions
Pigments
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Summary:Using a scorpionate-based complex, [FeIII(Tp)(CN)3]-, as a building block, a new cyanide-based molecular material [{FeIII(Tp)(CN)3}2NiII(H2O)2]·4H2O (1), which can be viewed as a lower dimensional model of Prussian blue analogues, was investigated as a lithium-ion storage host.
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc01374h