A [Fe III (Tp)(CN) 3 ] - scorpionate-based complex as a building block for designing ion storage hosts (Tp: hydrotrispyrazolylborate)

Using a scorpionate-based complex, [FeIII(Tp)(CN)3]-, as a building block, a new cyanide-based molecular material [{FeIII(Tp)(CN)3}2NiII(H2O)2]·4H2O (1), which can be viewed as a lower dimensional model of Prussian blue analogues, was investigated as a lithium-ion storage host.

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Published in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (41), p.5189-5192
Main Authors: Jiménez, Juan-Ramón, Sugahara, Akira, Okubo, Masashi, Yamada, Atsuo, Chamoreau, Lise-Marie, Lisnard, Laurent, Lescouëzec, Rodrigue
Format: Article
Language:English
Subjects:
Chemical Sciences
Coordination chemistry
Ion storage
Lithium ions
Pigments
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cited_by cdi_FETCH-LOGICAL-c385t-39e8903e42c38e6e0121ae7c09f68452d9c3ae2dd30530e6d5765ba392a53653
cites cdi_FETCH-LOGICAL-c385t-39e8903e42c38e6e0121ae7c09f68452d9c3ae2dd30530e6d5765ba392a53653
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container_issue 41
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container_title Chemical communications (Cambridge, England)
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creator Jiménez, Juan-Ramón
Sugahara, Akira
Okubo, Masashi
Yamada, Atsuo
Chamoreau, Lise-Marie
Lisnard, Laurent
Lescouëzec, Rodrigue
description Using a scorpionate-based complex, [FeIII(Tp)(CN)3]-, as a building block, a new cyanide-based molecular material [{FeIII(Tp)(CN)3}2NiII(H2O)2]·4H2O (1), which can be viewed as a lower dimensional model of Prussian blue analogues, was investigated as a lithium-ion storage host.
doi_str_mv 10.1039/c8cc01374h
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subjects Chemical Sciences
Coordination chemistry
Ion storage
Lithium ions
Pigments
title A [Fe III (Tp)(CN) 3 ] - scorpionate-based complex as a building block for designing ion storage hosts (Tp: hydrotrispyrazolylborate)
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