Estimation of effective elastic properties of polymer/clay nanocomposites: A parametric study

In this work, a 3D finite element model has been developed to compute the macroscopic elastic properties of polymer/clay nanocomposites (PCNs) from the microstructure morphologies and the elastic behaviour of each phase. Microstructural parameters of clay or clay stacks such as elastic properties, a...

Full description

Saved in:
Bibliographic Details
Published in:Composites. Part B, Engineering Engineering, 2018-11, Vol.152, p.139-150
Main Authors: Vo, Van Son, Nguyen, Vu-Hieu, Mahouche-Chergui, Samia, Carbonnier, Benjamin, Naili, Salah
Format: Article
Language:English
Subjects:
Biomechanics
Clay
Effective elastic properties
Exfoliated
Intercalated
Interphase
Mechanics
Partially exfoliated
Physics
Polymer
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:In this work, a 3D finite element model has been developed to compute the macroscopic elastic properties of polymer/clay nanocomposites (PCNs) from the microstructure morphologies and the elastic behaviour of each phase. Microstructural parameters of clay or clay stacks such as elastic properties, aspect ratio, interlayer spacing and clay volume fraction have been taken into account in the proposed models. A parametric study of the effect of these parameters on the macroscopic elastic properties of PCNs has been carefully investigated. The results show that the macroscopic rigidity of PCNs materials depends not only on the clay volume fraction but also on the dispersion state of clay platelets in the polymer matrix. An exfoliated structure may improve the macroscopic rigidity of PCNs much more efficiently than intercalated ones, particularly at high volume fraction of clays. The key role of interphase on the mechanical properties enhancement of PCNs has also been demonstrated. In addition, the partially exfoliated morphology, in which individual clay layers and intercalated blocks are simultaneously present in the polymer matrix, has been studied. The last morphology is commonly encountered in PCN processing, especially when high clay content is used. The comparison with the experimental and theoretical results extracted from the literature has been performed.
ISSN:1359-8368
1879-1069
DOI:10.1016/j.compositesb.2018.06.018