Controlled Reducibility of a Metal-Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption

Gas grabber: Reduction of the porous metal–organic framework MIL‐100(Fe) (see picture; X−: OH− or F−; red: O of trimesate ligands) to form coordinatively unsaturated sites at iron(II) (depicted as a violet circle) is essential for selective gas purification or the selective removal of unsaturated ga...

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Published in:Angewandte Chemie (International ed.) 2010-08, Vol.49 (34), p.5949-5952
Main Authors: Yoon, Ji Woong, Seo, You-Kyong, Hwang, Young Kyu, Chang, Jong-San, Leclerc, Hervé, Wuttke, Stefan, Bazin, Philippe, Vimont, Alexandre, Daturi, Marco, Bloch, Emily, Llewellyn, Philip L, Serre, Christian, Horcajada, Patricia, Grenèche, Jean-Marc, Rodrigues, Alirio E, Férey, Gérard
Format: Article
Language:English
Subjects:
Chemical Sciences
gas sorption
iron
metal-organic frameworks
porous materials
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Summary:Gas grabber: Reduction of the porous metal–organic framework MIL‐100(Fe) (see picture; X−: OH− or F−; red: O of trimesate ligands) to form coordinatively unsaturated sites at iron(II) (depicted as a violet circle) is essential for selective gas purification or the selective removal of unsaturated gas impurities.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201001230