Highly efficient Tsuji-Trost allylation in water catalyzed by Pd-nanoparticles

Palladium nanoparticles stabilized by poly(vinylpyrrolidone) catalyze Tsuji-Trost allylations in water with very high turnover numbers. The di-allylation of methylene active compounds and the allylation of bio-based phenols was performed in high yield. The allylation of lignin showed a high selectiv...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (37), p.5175-5178
Main Authors: Llevot, A, Monney, B, Sehlinger, A, Behrens, S, Meier, M A R
Format: Article
Language:English
Subjects:
Chemical Sciences
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Summary:Palladium nanoparticles stabilized by poly(vinylpyrrolidone) catalyze Tsuji-Trost allylations in water with very high turnover numbers. The di-allylation of methylene active compounds and the allylation of bio-based phenols was performed in high yield. The allylation of lignin showed a high selectivity towards the phenolic OH groups.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc02380d