Investigation of methoxypropionitrile as co-solvent for ethylene carbonate based electrolyte in supercapacitors. A safe and wide temperature range electrolyte

• Published in: Electrochimica acta 2013-03, Vol.93, p.1-7
• Main Authors: Perricone, E., Chamas, M., Cointeaux, L., Leprêtre, J.-C., Judeinstein, P., Azais, P., Béguin, F., Alloin, F.
• Format: Article
• Language: English
• Subjects: Capacitors; Carbonates; Chemical Sciences; Electrochemical stability; Electrolyte; Electrolytes; Ethylene; Liquids; Polycarbonates; Solubility; Solvent; Supercapacitor; Supercapacitors
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2013.01.084

► Electrolytes EC/MP exhibit relevant properties for supercapacitor application. ► Secure electrolytes can be obtain with high conductivities in a large temperature window. ► Spiro-(1,1′)-bipyrrolidinium tetrafluoroborate (SBPBF4) as salt permit to improve cycle life, and performances at low temperature. The performances obtained with methoxypropionitrile/ethylene carbonate mixture based electrolytes were investigated in supercapacitor application. The incorporation of methoxypropionitrile allows a good compromise between electrochemical performances and safety issue to be exhibited in a wide temperature range. This improvement is associated with the decrease of electrolyte viscosity without compromising the salt solubility and dissociation. The highest conductivity values, 20mScm−1 at 30°C compared to 14mScm−1 in PC (propylene carbonate), were obtained with both 1M tetraethylammonium tetrafluoroborate (TEABF4) and spiro-(1,1′)-bipyrrolidium tetrafluoroborate (SBPBF4) salts. Bulk liquid state was conserved for these electrolytes in a wide temperature range. Then, interesting electrolyte conductivities were obtained at low temperature (5.2mScm−1 at −25°C) which is twice that of PC+TEABF4 1M electrolyte at the same conditions. Moreover, the capacitor performance of EC/MP based electrolyte is better than PC one at room temperature.