A hexameric [MnNa 6 ] wheel based on [MnO] 7+ sub-units

A novel hexameric [MnNa ] wheel-like aggregate consisting of [MnO] triangles is reported. It is the second highest nuclearity oxime-based Mn cluster, the largest member of the recently-developed family of molecular oligomers based on [MnO] triangles, and the only one with a wheel-like metal topology...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2016-10, Vol.52 (87), p.12829-12832
Main Authors: Manoli, Maria, Inglis, Ross, Piligkos, Stergios, Yanhua, Lan, Wernsdorfer, Wolfgang, Brechin, Euan K, Tasiopoulos, Anastasios J
Format: Article
Language:English
Subjects:
Aggregates
Clusters
Oligomers
Physics
Topology
Triangles
Wheels
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Summary:A novel hexameric [MnNa ] wheel-like aggregate consisting of [MnO] triangles is reported. It is the second highest nuclearity oxime-based Mn cluster, the largest member of the recently-developed family of molecular oligomers based on [MnO] triangles, and the only one with a wheel-like metal topology.
ISSN:1359-7345
1364-548X
DOI:10.1039/C6CC06644E