Poly(1,4-butadiene)-graft-poly(L-lactide) via the grafting-from strategy

Poly(1,4-butadiene)- graft -poly( L -lactide) copolymers were efficiently prepared via the grafting-from strategy using a combination of ring-opening metathesis polymerization (ROMP) of a hydroxyl-functionalized cyclobutene monomer and organocatalyzed ring-opening polymerization (ROP) of L -lactide....

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Bibliographic Details
Published in:Polymer bulletin (Berlin, Germany) Germany), 2017-11, Vol.74 (11), p.4415-4422
Main Authors: Leroux, Flavien, Montembault, Véronique, Piogé, Sandie, Pascual, Sagrario, Fontaine, Laurent
Format: Article
Language:English
Subjects:
Butadiene
Characterization and Evaluation of Materials
Chemical Sciences
Chemistry
Chemistry and Materials Science
Chromatography
Complex Fluids and Microfluidics
Copolymers
Graft copolymers
Laboratories
Lasers
Metathesis
Nitrogen
NMR
Nuclear magnetic resonance
Organic Chemistry
Original Paper
Physical Chemistry
Polyesters
Polymer Sciences
Polymerization
Polymers
Ring opening polymerization
Soft and Granular Matter
Solvents
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Summary:Poly(1,4-butadiene)- graft -poly( L -lactide) copolymers were efficiently prepared via the grafting-from strategy using a combination of ring-opening metathesis polymerization (ROMP) of a hydroxyl-functionalized cyclobutene monomer and organocatalyzed ring-opening polymerization (ROP) of L -lactide. The copolymers were characterized by NMR, MALDI-TOF, SEC, TGA, and DSC demonstrating that well-defined polyester-grafted poly(1,4-butadiene) were obtained through the reported methodology.
ISSN:0170-0839
1436-2449
DOI:10.1007/s00289-017-1961-y