Structural and functional modifications induced by X-ray nanopatterning in Bi-2212 single crystals

• Published in: CrystEngComm 2018, Vol.2 (42), p.6667-6676
• Main Authors: Bonino, Valentina, Agostino, Angelo, Prestipino, Carmelo, Hernandez, Olivier, Fretto, Matteo, Mino, Lorenzo, Truccato, Marco
• Format: Article
• Language: English
• Subjects: Bismuth strontium calcium copper oxide; Carrier density; Chemical Sciences; Cristallography; Crystal defects; Grain boundaries; Microcrystals; Photoresists; Single crystals; X ray irradiation
• ISSN: 1466-8033; 1466-8033
• DOI: 10.1039/c8ce01183d

We have investigated the modifications induced in the high- T c superconductor Bi 2 Sr 2 CaCu 2 O 8+ δ (Bi-2212) by X-ray nanopatterning, which is an innovative, photoresist-free, direct-writing approach recently used to fabricate proof-of-concept electrical devices [Truccato et al. , Nano Lett. , 2016, 16 , 1669]. By means of combined synchrotron microdiffraction and electrical transport measurements carried out on the same Bi-2212 microcrystal, we show that hard X-ray irradiation with fluences of the order of 10 12 J m −2 , corresponding to doses of the order of 10 13 Gy, induces crystal fragmentation into multiple subdomains and decreases the carrier density of the system. We ascertain that the synergistic action of grain boundaries and of oxygen removal from the material dramatically changes the properties of Bi-2212 both in the normal and in the superconducting state. This special feature of X-ray nanopatterning introduces an opportunity that could be exploited to finely tune material structural defects according to the desired properties. X-ray nanopatterning induces both mosaicity increase and oxygen depletion in the high- T c superconductor Bi 2 Sr 2 CaCu 2 O 8+ δ .