Manganese and iron flavonolates as flavonol 2,4-dioxygenase mimics

Mononuclear manganese(II) and iron(III) flavonolates were synthesized as synthetic enzyme-substrate complexes, and their oxygenation reactions as biomimetic functional models with relevance to flavonol 2,4-dioxygenases are briefly described.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2007-01 (48), p.5235-5237
Main Authors: Kaizer, József, Baráth, Gábor, Pap, József, Speier, Gábor, Giorgi, Michel, Réglier, Marius
Format: Article
Language:English
Subjects:
Catalysis
Chemical Sciences
Coordination chemistry
Crystallography, X-Ray
Dioxygenases - chemistry
Flavonoids - chemistry
Inorganic chemistry
Iron - chemistry
Kinetics
Manganese - chemistry
Models, Biological
Models, Molecular
Molecular Mimicry
Molecular Structure
Organic chemistry
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
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Description
Summary:Mononuclear manganese(II) and iron(III) flavonolates were synthesized as synthetic enzyme-substrate complexes, and their oxygenation reactions as biomimetic functional models with relevance to flavonol 2,4-dioxygenases are briefly described.
ISSN:1359-7345
1364-548X
DOI:10.1039/b711864c