Loading…
[N,P]-pyrrole-phosphine ligand: An efficient and robust ligand for Ru-catalyzed transfer hydrogenation microwave-assisted reactions
A pyrrolyl-containing [N-P]-ligand (L1) and [Ru] were evaluated as catalytic system in transfer hydrogenation reaction of ketones. A comparison between microwave irradiation vs conventional heating conditions indicates that MW can be successfully used as energy source, improving the reaction time. T...
Saved in:
| Published in: | Catalysis communications 2018-09, Vol.115, p.49-54 |
|---|---|
| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c377t-59f2e0b7293cf1a4172f88f21cb90288fdfe04e32942062ef19a833af51cb1203 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c377t-59f2e0b7293cf1a4172f88f21cb90288fdfe04e32942062ef19a833af51cb1203 |
| container_end_page | 54 |
| container_issue | |
| container_start_page | 49 |
| container_title | Catalysis communications |
| container_volume | 115 |
| creator | Sánchez-Rodríguez, E.P. Fragoso-Medina, A.J. Ramírez-Meneses, E. Gouygou, M. Ortega-Alfaro, M.C. López-Cortés, J.G. |
| description | A pyrrolyl-containing [N-P]-ligand (L1) and [Ru] were evaluated as catalytic system in transfer hydrogenation reaction of ketones. A comparison between microwave irradiation vs conventional heating conditions indicates that MW can be successfully used as energy source, improving the reaction time. The L1/Ru(II) proved to be an active, efficient and robust catalytic system. The scope of this catalytic system was evaluated using a diversity of substrates that include electron-withdrawing and electron-donor groups achieving a range of 65 to 95% conversion. Moreover, the catalytic system showed good activity even with highly sterically hindered ketones.
[Display omitted]
•Transfer catalytic hydrogenation microwave promoted.•The L1/Ru(II) proved to be an active, efficient and robust catalytic system.•High conversions were obtained with hindered substrates. |
| doi_str_mv | 10.1016/j.catcom.2018.07.009 |
| format | article |
| fullrecord | <record><control><sourceid>hal_cross</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_01949858v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S156673671830253X</els_id><sourcerecordid>oai_HAL_hal_01949858v1</sourcerecordid><originalsourceid>FETCH-LOGICAL-c377t-59f2e0b7293cf1a4172f88f21cb90288fdfe04e32942062ef19a833af51cb1203</originalsourceid><addsrcrecordid>eNp9kE1LAzEQhhdRUKv_wEOuglnzsbvZeBCKqBWKiuhJJKTZiU3ZbkqyVurVP26WikdPM8y873w8WXZCSU4Jrc4XudG98cucEVrnROSEyJ3sgNaCYy5JuZvysqqw4JXYzw5jXJBkk1weZN-v92ePb3i1CcG3gFdzH1dz1wFq3bvumgs07hBY64yDrkepgoKffcT-t4-sD-jpA6f9ut18QYP6oLtoIaD5pgn-HTrdO9-hpTPBf-o1YB2ji31SBtBm6MWjbM_qNsLxbxxlLzfXz1cTPH24vbsaT7HhQvS4lJYBmQkmubFUF1QwW9eWUTOThKWssUAK4EwWjFQMLJW65lzbMikoI3yUnW7nznWrVsEtddgor52ajKdqqBEqC1mX9ZombbHVprNjDGD_DJSoAbpaqC10NUBXRKgEPdkutzZIf6wdBBUHcgYaF8D0qvHu_wE_De2PAA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>[N,P]-pyrrole-phosphine ligand: An efficient and robust ligand for Ru-catalyzed transfer hydrogenation microwave-assisted reactions</title><source>ScienceDirect Freedom Collection</source><creator>Sánchez-Rodríguez, E.P. ; Fragoso-Medina, A.J. ; Ramírez-Meneses, E. ; Gouygou, M. ; Ortega-Alfaro, M.C. ; López-Cortés, J.G.</creator><creatorcontrib>Sánchez-Rodríguez, E.P. ; Fragoso-Medina, A.J. ; Ramírez-Meneses, E. ; Gouygou, M. ; Ortega-Alfaro, M.C. ; López-Cortés, J.G.</creatorcontrib><description>A pyrrolyl-containing [N-P]-ligand (L1) and [Ru] were evaluated as catalytic system in transfer hydrogenation reaction of ketones. A comparison between microwave irradiation vs conventional heating conditions indicates that MW can be successfully used as energy source, improving the reaction time. The L1/Ru(II) proved to be an active, efficient and robust catalytic system. The scope of this catalytic system was evaluated using a diversity of substrates that include electron-withdrawing and electron-donor groups achieving a range of 65 to 95% conversion. Moreover, the catalytic system showed good activity even with highly sterically hindered ketones.
[Display omitted]
•Transfer catalytic hydrogenation microwave promoted.•The L1/Ru(II) proved to be an active, efficient and robust catalytic system.•High conversions were obtained with hindered substrates.</description><identifier>ISSN: 1566-7367</identifier><identifier>EISSN: 1873-3905</identifier><identifier>DOI: 10.1016/j.catcom.2018.07.009</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>[N,P]-ligand ; Chemical Sciences ; Coordination chemistry ; Microwave ; Ruthenium ; Transfer-hydrogenation</subject><ispartof>Catalysis communications, 2018-09, Vol.115, p.49-54</ispartof><rights>2018 Elsevier B.V.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c377t-59f2e0b7293cf1a4172f88f21cb90288fdfe04e32942062ef19a833af51cb1203</citedby><cites>FETCH-LOGICAL-c377t-59f2e0b7293cf1a4172f88f21cb90288fdfe04e32942062ef19a833af51cb1203</cites><orcidid>0000-0002-4508-117X ; 0000-0001-6590-3671</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://hal.science/hal-01949858$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Sánchez-Rodríguez, E.P.</creatorcontrib><creatorcontrib>Fragoso-Medina, A.J.</creatorcontrib><creatorcontrib>Ramírez-Meneses, E.</creatorcontrib><creatorcontrib>Gouygou, M.</creatorcontrib><creatorcontrib>Ortega-Alfaro, M.C.</creatorcontrib><creatorcontrib>López-Cortés, J.G.</creatorcontrib><title>[N,P]-pyrrole-phosphine ligand: An efficient and robust ligand for Ru-catalyzed transfer hydrogenation microwave-assisted reactions</title><title>Catalysis communications</title><description>A pyrrolyl-containing [N-P]-ligand (L1) and [Ru] were evaluated as catalytic system in transfer hydrogenation reaction of ketones. A comparison between microwave irradiation vs conventional heating conditions indicates that MW can be successfully used as energy source, improving the reaction time. The L1/Ru(II) proved to be an active, efficient and robust catalytic system. The scope of this catalytic system was evaluated using a diversity of substrates that include electron-withdrawing and electron-donor groups achieving a range of 65 to 95% conversion. Moreover, the catalytic system showed good activity even with highly sterically hindered ketones.
[Display omitted]
•Transfer catalytic hydrogenation microwave promoted.•The L1/Ru(II) proved to be an active, efficient and robust catalytic system.•High conversions were obtained with hindered substrates.</description><subject>[N,P]-ligand</subject><subject>Chemical Sciences</subject><subject>Coordination chemistry</subject><subject>Microwave</subject><subject>Ruthenium</subject><subject>Transfer-hydrogenation</subject><issn>1566-7367</issn><issn>1873-3905</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhhdRUKv_wEOuglnzsbvZeBCKqBWKiuhJJKTZiU3ZbkqyVurVP26WikdPM8y873w8WXZCSU4Jrc4XudG98cucEVrnROSEyJ3sgNaCYy5JuZvysqqw4JXYzw5jXJBkk1weZN-v92ePb3i1CcG3gFdzH1dz1wFq3bvumgs07hBY64yDrkepgoKffcT-t4-sD-jpA6f9ut18QYP6oLtoIaD5pgn-HTrdO9-hpTPBf-o1YB2ji31SBtBm6MWjbM_qNsLxbxxlLzfXz1cTPH24vbsaT7HhQvS4lJYBmQkmubFUF1QwW9eWUTOThKWssUAK4EwWjFQMLJW65lzbMikoI3yUnW7nznWrVsEtddgor52ajKdqqBEqC1mX9ZombbHVprNjDGD_DJSoAbpaqC10NUBXRKgEPdkutzZIf6wdBBUHcgYaF8D0qvHu_wE_De2PAA</recordid><startdate>20180901</startdate><enddate>20180901</enddate><creator>Sánchez-Rodríguez, E.P.</creator><creator>Fragoso-Medina, A.J.</creator><creator>Ramírez-Meneses, E.</creator><creator>Gouygou, M.</creator><creator>Ortega-Alfaro, M.C.</creator><creator>López-Cortés, J.G.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-4508-117X</orcidid><orcidid>https://orcid.org/0000-0001-6590-3671</orcidid></search><sort><creationdate>20180901</creationdate><title>[N,P]-pyrrole-phosphine ligand: An efficient and robust ligand for Ru-catalyzed transfer hydrogenation microwave-assisted reactions</title><author>Sánchez-Rodríguez, E.P. ; Fragoso-Medina, A.J. ; Ramírez-Meneses, E. ; Gouygou, M. ; Ortega-Alfaro, M.C. ; López-Cortés, J.G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c377t-59f2e0b7293cf1a4172f88f21cb90288fdfe04e32942062ef19a833af51cb1203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>[N,P]-ligand</topic><topic>Chemical Sciences</topic><topic>Coordination chemistry</topic><topic>Microwave</topic><topic>Ruthenium</topic><topic>Transfer-hydrogenation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sánchez-Rodríguez, E.P.</creatorcontrib><creatorcontrib>Fragoso-Medina, A.J.</creatorcontrib><creatorcontrib>Ramírez-Meneses, E.</creatorcontrib><creatorcontrib>Gouygou, M.</creatorcontrib><creatorcontrib>Ortega-Alfaro, M.C.</creatorcontrib><creatorcontrib>López-Cortés, J.G.</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Catalysis communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sánchez-Rodríguez, E.P.</au><au>Fragoso-Medina, A.J.</au><au>Ramírez-Meneses, E.</au><au>Gouygou, M.</au><au>Ortega-Alfaro, M.C.</au><au>López-Cortés, J.G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>[N,P]-pyrrole-phosphine ligand: An efficient and robust ligand for Ru-catalyzed transfer hydrogenation microwave-assisted reactions</atitle><jtitle>Catalysis communications</jtitle><date>2018-09-01</date><risdate>2018</risdate><volume>115</volume><spage>49</spage><epage>54</epage><pages>49-54</pages><issn>1566-7367</issn><eissn>1873-3905</eissn><abstract>A pyrrolyl-containing [N-P]-ligand (L1) and [Ru] were evaluated as catalytic system in transfer hydrogenation reaction of ketones. A comparison between microwave irradiation vs conventional heating conditions indicates that MW can be successfully used as energy source, improving the reaction time. The L1/Ru(II) proved to be an active, efficient and robust catalytic system. The scope of this catalytic system was evaluated using a diversity of substrates that include electron-withdrawing and electron-donor groups achieving a range of 65 to 95% conversion. Moreover, the catalytic system showed good activity even with highly sterically hindered ketones.
[Display omitted]
•Transfer catalytic hydrogenation microwave promoted.•The L1/Ru(II) proved to be an active, efficient and robust catalytic system.•High conversions were obtained with hindered substrates.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.catcom.2018.07.009</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-4508-117X</orcidid><orcidid>https://orcid.org/0000-0001-6590-3671</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1566-7367 |
| ispartof | Catalysis communications, 2018-09, Vol.115, p.49-54 |
| issn | 1566-7367 1873-3905 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_01949858v1 |
| source | ScienceDirect Freedom Collection |
| subjects | [N,P]-ligand Chemical Sciences Coordination chemistry Microwave Ruthenium Transfer-hydrogenation |
| title | [N,P]-pyrrole-phosphine ligand: An efficient and robust ligand for Ru-catalyzed transfer hydrogenation microwave-assisted reactions |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T12%3A26%3A23IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-hal_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=%5BN,P%5D-pyrrole-phosphine%20ligand:%20An%20efficient%20and%20robust%20ligand%20for%20Ru-catalyzed%20transfer%20hydrogenation%20microwave-assisted%20reactions&rft.jtitle=Catalysis%20communications&rft.au=S%C3%A1nchez-Rodr%C3%ADguez,%20E.P.&rft.date=2018-09-01&rft.volume=115&rft.spage=49&rft.epage=54&rft.pages=49-54&rft.issn=1566-7367&rft.eissn=1873-3905&rft_id=info:doi/10.1016/j.catcom.2018.07.009&rft_dat=%3Chal_cross%3Eoai_HAL_hal_01949858v1%3C/hal_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c377t-59f2e0b7293cf1a4172f88f21cb90288fdfe04e32942062ef19a833af51cb1203%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |