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Annelated tricyclic thiophenes and their photophysical properties

[Display omitted] Photochemical oxidative cyclization of 3-[(E)-2-(3,4-di-methoxyphenyl)vinyl]thiophene and its 15-crown-5-analogue (15-[(E)-2-(3-thienyl)vinyl]-2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecine) affords the isomeric thiophene-containing fused aromatic compounds d...

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Published in:Mendeleev communications 2018-09, Vol.28 (5), p.543-545
Main Authors: Lukovskaya, Elena V., Dyachenko, Natalya V., Khoroshutin, Andrey V., Bobyleva, Alla A., Anisimov, Alexander V., Karnoukhova, Valentina A., Jonusauskas, Gediminas, Fedorov, Yurii V., Fedorova, Olga A.
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Language:English
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Summary:[Display omitted] Photochemical oxidative cyclization of 3-[(E)-2-(3,4-di-methoxyphenyl)vinyl]thiophene and its 15-crown-5-analogue (15-[(E)-2-(3-thienyl)vinyl]-2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecine) affords the isomeric thiophene-containing fused aromatic compounds demonstrating photophysical properties different from those of initial styryl derivatives. E-Configuration of the initial styryl dye, 3-[(E)-2-(3,4-dimethoxyphenyl)vinyl]thiophene, has been proved by X-ray analysis.
ISSN:0959-9436
1364-551X
DOI:10.1016/j.mencom.2018.09.032