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Structural Confinement toward Giant Enhancement of Red Emission in Mn 2+ ‐Based Phosphors
Structural confinement effect on a pair of Eu 2+ and Mn 2+ optical centers is developed to realize the greatly enhanced red emission attributed to the 4 T 1 ( 4 G)– 6 A 1 ( 6 S) transition of Mn 2+ ions. Sr 9 Mn 1.26(2) Li 0.24(2) (PO 4− δ ) 7 , when it is doped with Eu 2+ , emerges as a new red‐emi...
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| Published in: | Advanced functional materials 2018-10, Vol.28 (41) |
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| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c1181-47705846697824387092cd6d4f69a5de71cfa0f6a01074068bce785b236e60243 |
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| container_issue | 41 |
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| container_title | Advanced functional materials |
| container_volume | 28 |
| creator | Zhang, Zhichao Ma, Chonggeng Gautier, Romain Molokeev, Maxim S. Liu, Quanlin Xia, Zhiguo |
| description | Structural confinement effect on a pair of Eu
2+
and Mn
2+
optical centers is developed to realize the greatly enhanced red emission attributed to the
4
T
1
(
4
G)–
6
A
1
(
6
S) transition of Mn
2+
ions. Sr
9
Mn
1.26(2)
Li
0.24(2)
(PO
4−
δ
)
7
, when it is doped with Eu
2+
, emerges as a new red‐emitting phosphor, and the intensity dependence of such a red emission on the trace amounts of Eu
2+
doping is quantitatively analyzed with a combined experimental and theoretical methods. The modeling result confirms the validity of this proposed design strategy, and the intrinsic high‐efficient Eu
2+
–Mn
2+
energy transfer process can be elucidated by the structural confinement effect featured as some Sr (Eu) close to Mn atoms. The results can initiate the exploration of Mn
2+
‐based red phosphors for pc‐white light‐emitting diodes applications, and such a strategy can be easily expanded to other systems, thus opening a new perspective for the development of luminescence materials. |
| doi_str_mv | 10.1002/adfm.201804150 |
| format | article |
| fullrecord | <record><control><sourceid>hal_cross</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_01972224v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>oai_HAL_hal_01972224v1</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1181-47705846697824387092cd6d4f69a5de71cfa0f6a01074068bce785b236e60243</originalsourceid><addsrcrecordid>eNo9kE1LwzAYx4MoOKdXz7mKdD5PmibpcY65CRPFFxA8lKxNaGVNRtIp3vwIfkY_iR2TnZ6X_8vhR8g5wggB2JWubDtigAo4ZnBABihQJCkwdbjf8fWYnMT4DoBSpnxA3p66sCm7TdArOvHONs60xnW08586VHTW6P6Yulq7cid4Sx9NRadtE2PjHW0cvXOUXdLf759rHXvpofZxXfsQT8mR1atozv7nkLzcTJ8n82RxP7udjBdJiagw4VJCprgQuVSMp0pCzspKVNyKXGeVkVhaDVZoQJAchFqWRqpsyVJhBPSJIbnY9dZ6VaxD0-rwVXjdFPPxotj-AHPJGOMf2HtHO28ZfIzB2H0AodhiLLYYiz3G9A9o0GR7</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Structural Confinement toward Giant Enhancement of Red Emission in Mn 2+ ‐Based Phosphors</title><source>Wiley</source><creator>Zhang, Zhichao ; Ma, Chonggeng ; Gautier, Romain ; Molokeev, Maxim S. ; Liu, Quanlin ; Xia, Zhiguo</creator><creatorcontrib>Zhang, Zhichao ; Ma, Chonggeng ; Gautier, Romain ; Molokeev, Maxim S. ; Liu, Quanlin ; Xia, Zhiguo</creatorcontrib><description>Structural confinement effect on a pair of Eu
2+
and Mn
2+
optical centers is developed to realize the greatly enhanced red emission attributed to the
4
T
1
(
4
G)–
6
A
1
(
6
S) transition of Mn
2+
ions. Sr
9
Mn
1.26(2)
Li
0.24(2)
(PO
4−
δ
)
7
, when it is doped with Eu
2+
, emerges as a new red‐emitting phosphor, and the intensity dependence of such a red emission on the trace amounts of Eu
2+
doping is quantitatively analyzed with a combined experimental and theoretical methods. The modeling result confirms the validity of this proposed design strategy, and the intrinsic high‐efficient Eu
2+
–Mn
2+
energy transfer process can be elucidated by the structural confinement effect featured as some Sr (Eu) close to Mn atoms. The results can initiate the exploration of Mn
2+
‐based red phosphors for pc‐white light‐emitting diodes applications, and such a strategy can be easily expanded to other systems, thus opening a new perspective for the development of luminescence materials.</description><identifier>ISSN: 1616-301X</identifier><identifier>EISSN: 1616-3028</identifier><identifier>DOI: 10.1002/adfm.201804150</identifier><language>eng</language><publisher>Wiley</publisher><subject>Condensed Matter ; Materials Science ; Physics</subject><ispartof>Advanced functional materials, 2018-10, Vol.28 (41)</ispartof><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1181-47705846697824387092cd6d4f69a5de71cfa0f6a01074068bce785b236e60243</citedby><cites>FETCH-LOGICAL-c1181-47705846697824387092cd6d4f69a5de71cfa0f6a01074068bce785b236e60243</cites><orcidid>0000-0002-9670-3223</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,778,782,883,27907,27908</link.rule.ids><backlink>$$Uhttps://hal.science/hal-01972224$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Zhichao</creatorcontrib><creatorcontrib>Ma, Chonggeng</creatorcontrib><creatorcontrib>Gautier, Romain</creatorcontrib><creatorcontrib>Molokeev, Maxim S.</creatorcontrib><creatorcontrib>Liu, Quanlin</creatorcontrib><creatorcontrib>Xia, Zhiguo</creatorcontrib><title>Structural Confinement toward Giant Enhancement of Red Emission in Mn 2+ ‐Based Phosphors</title><title>Advanced functional materials</title><description>Structural confinement effect on a pair of Eu
2+
and Mn
2+
optical centers is developed to realize the greatly enhanced red emission attributed to the
4
T
1
(
4
G)–
6
A
1
(
6
S) transition of Mn
2+
ions. Sr
9
Mn
1.26(2)
Li
0.24(2)
(PO
4−
δ
)
7
, when it is doped with Eu
2+
, emerges as a new red‐emitting phosphor, and the intensity dependence of such a red emission on the trace amounts of Eu
2+
doping is quantitatively analyzed with a combined experimental and theoretical methods. The modeling result confirms the validity of this proposed design strategy, and the intrinsic high‐efficient Eu
2+
–Mn
2+
energy transfer process can be elucidated by the structural confinement effect featured as some Sr (Eu) close to Mn atoms. The results can initiate the exploration of Mn
2+
‐based red phosphors for pc‐white light‐emitting diodes applications, and such a strategy can be easily expanded to other systems, thus opening a new perspective for the development of luminescence materials.</description><subject>Condensed Matter</subject><subject>Materials Science</subject><subject>Physics</subject><issn>1616-301X</issn><issn>1616-3028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNo9kE1LwzAYx4MoOKdXz7mKdD5PmibpcY65CRPFFxA8lKxNaGVNRtIp3vwIfkY_iR2TnZ6X_8vhR8g5wggB2JWubDtigAo4ZnBABihQJCkwdbjf8fWYnMT4DoBSpnxA3p66sCm7TdArOvHONs60xnW08586VHTW6P6Yulq7cid4Sx9NRadtE2PjHW0cvXOUXdLf759rHXvpofZxXfsQT8mR1atozv7nkLzcTJ8n82RxP7udjBdJiagw4VJCprgQuVSMp0pCzspKVNyKXGeVkVhaDVZoQJAchFqWRqpsyVJhBPSJIbnY9dZ6VaxD0-rwVXjdFPPxotj-AHPJGOMf2HtHO28ZfIzB2H0AodhiLLYYiz3G9A9o0GR7</recordid><startdate>201810</startdate><enddate>201810</enddate><creator>Zhang, Zhichao</creator><creator>Ma, Chonggeng</creator><creator>Gautier, Romain</creator><creator>Molokeev, Maxim S.</creator><creator>Liu, Quanlin</creator><creator>Xia, Zhiguo</creator><general>Wiley</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-9670-3223</orcidid></search><sort><creationdate>201810</creationdate><title>Structural Confinement toward Giant Enhancement of Red Emission in Mn 2+ ‐Based Phosphors</title><author>Zhang, Zhichao ; Ma, Chonggeng ; Gautier, Romain ; Molokeev, Maxim S. ; Liu, Quanlin ; Xia, Zhiguo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1181-47705846697824387092cd6d4f69a5de71cfa0f6a01074068bce785b236e60243</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Condensed Matter</topic><topic>Materials Science</topic><topic>Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Zhichao</creatorcontrib><creatorcontrib>Ma, Chonggeng</creatorcontrib><creatorcontrib>Gautier, Romain</creatorcontrib><creatorcontrib>Molokeev, Maxim S.</creatorcontrib><creatorcontrib>Liu, Quanlin</creatorcontrib><creatorcontrib>Xia, Zhiguo</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Advanced functional materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Zhichao</au><au>Ma, Chonggeng</au><au>Gautier, Romain</au><au>Molokeev, Maxim S.</au><au>Liu, Quanlin</au><au>Xia, Zhiguo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structural Confinement toward Giant Enhancement of Red Emission in Mn 2+ ‐Based Phosphors</atitle><jtitle>Advanced functional materials</jtitle><date>2018-10</date><risdate>2018</risdate><volume>28</volume><issue>41</issue><issn>1616-301X</issn><eissn>1616-3028</eissn><abstract>Structural confinement effect on a pair of Eu
2+
and Mn
2+
optical centers is developed to realize the greatly enhanced red emission attributed to the
4
T
1
(
4
G)–
6
A
1
(
6
S) transition of Mn
2+
ions. Sr
9
Mn
1.26(2)
Li
0.24(2)
(PO
4−
δ
)
7
, when it is doped with Eu
2+
, emerges as a new red‐emitting phosphor, and the intensity dependence of such a red emission on the trace amounts of Eu
2+
doping is quantitatively analyzed with a combined experimental and theoretical methods. The modeling result confirms the validity of this proposed design strategy, and the intrinsic high‐efficient Eu
2+
–Mn
2+
energy transfer process can be elucidated by the structural confinement effect featured as some Sr (Eu) close to Mn atoms. The results can initiate the exploration of Mn
2+
‐based red phosphors for pc‐white light‐emitting diodes applications, and such a strategy can be easily expanded to other systems, thus opening a new perspective for the development of luminescence materials.</abstract><pub>Wiley</pub><doi>10.1002/adfm.201804150</doi><orcidid>https://orcid.org/0000-0002-9670-3223</orcidid></addata></record> |
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| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_01972224v1 |
| source | Wiley |
| subjects | Condensed Matter Materials Science Physics |
| title | Structural Confinement toward Giant Enhancement of Red Emission in Mn 2+ ‐Based Phosphors |
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