Cover Feature: Magnetic Slow Relaxation in a Metal–Organic Framework Made of Chains of Ferromagnetically Coupled Single‐Molecule Magnets (Chem. Eur. J. 27/2018)

Ferromagnetic interactions induced by metal—organic framework (MOF) architecture turn a poor single‐molecule magnet (SMM) into a slow relaxing material. The MOF is made of nine‐coordinated DyIII magnetic building blocks (MBBs) with poor intrinsic SMM behavior. However, the MOF architecture constrain...

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Bibliographic Details
Published in:Chemistry - A European Journal 2018-05, Vol.24 (27), p.6864-6864
Main Authors: Huang, Gang, Fernandez‐Garcia, Guglielmo, Badiane, Insa, Camarra, Magatte, Freslon, Stéphane, Guillou, Olivier, Daiguebonne, Carole, Totti, Federico, Cador, Olivier, Guizouarn, Thierry, Le Guennic, Boris, Bernot, Kevin
Format: Article
Language:English
Subjects:
Chemical Sciences
Coordination chemistry
ferromagnetic coupling
lanthanides
metal–organic frameworks
single-chain magnets
single-molecule magnets
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Summary:Ferromagnetic interactions induced by metal—organic framework (MOF) architecture turn a poor single‐molecule magnet (SMM) into a slow relaxing material. The MOF is made of nine‐coordinated DyIII magnetic building blocks (MBBs) with poor intrinsic SMM behavior. However, the MOF architecture constrains the MBBs in a one‐dimensional structure that induces a ferromagnetic coupling between them. More information can be found in the Full Paper by B. Le Guennic, K. Bernot et al. on page 6983.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201801396