Chiral Lithium Amides: Tuning Asymmetric Synthesis on the Basis of Structural Parameters

An overview on the structural arrangements adopted by Chiral Lithium Amides (CLAs), alone or in mixed complexes, is presented. These species are important reagents for asymmetric synthesis and understanding their organization is essential to improve their design and the reaction conditions. An overv...

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Published in:Chemical record 2017-06, Vol.17 (6), p.622-639
Main Authors: Harrison‐Marchand, Anne, Barozzino‐Consiglio, Gabriella, Maddaluno, Jacques
Format: Article
Language:English
Subjects:
aggregation
Amides
Asymmetric synthesis
Chemical Sciences
Chiral lithium amide
crystallography
Design improvements
Lithium
NMR
Organic chemistry
Reagents
Structure/Reactivity relationship
Synthesis
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description An overview on the structural arrangements adopted by Chiral Lithium Amides (CLAs), alone or in mixed complexes, is presented. These species are important reagents for asymmetric synthesis and understanding their organization is essential to improve their design and the reaction conditions. An overview on the structural arrangements adopted by Chiral Lithium Amides (CLAs), alone or in mixed complexes, is presented. These species are important reagents for asymmetric synthesis and understanding their organization is essential to improve their design and the reaction conditions.
doi_str_mv 10.1002/tcr.201600115
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subjects aggregation
Amides
Asymmetric synthesis
Chemical Sciences
Chiral lithium amide
crystallography
Design improvements
Lithium
NMR
Organic chemistry
Reagents
Structure/Reactivity relationship
Synthesis
title Chiral Lithium Amides: Tuning Asymmetric Synthesis on the Basis of Structural Parameters
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