Insulator-to-Proton-Conductor Transition in a Dense Metal–Organic Framework

Metal–organic frameworks (MOFs) are prone to exhibit phase transitions under stimuli such as changes in pressure, temperature, or gas sorption because of their flexible and responsive structures. Here we report that a dense MOF, ((CH3)2NH2)2­[Li2Zr­(C2O4)4], exhibits an abrupt increase in proton con...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2015-05, Vol.137 (20), p.6428-6431
Main Authors: Tominaka, Satoshi, Coudert, François-Xavier, Dao, Thang D, Nagao, Tadaaki, Cheetham, Anthony K
Format: Article
Language:English
Subjects:
Chemical Sciences
Material chemistry
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Summary:Metal–organic frameworks (MOFs) are prone to exhibit phase transitions under stimuli such as changes in pressure, temperature, or gas sorption because of their flexible and responsive structures. Here we report that a dense MOF, ((CH3)2NH2)2­[Li2Zr­(C2O4)4], exhibits an abrupt increase in proton conductivity from
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.5b02777