Insulator-to-Proton-Conductor Transition in a Dense Metal–Organic Framework

Metal–organic frameworks (MOFs) are prone to exhibit phase transitions under stimuli such as changes in pressure, temperature, or gas sorption because of their flexible and responsive structures. Here we report that a dense MOF, ((CH3)2NH2)2­[Li2Zr­(C2O4)4], exhibits an abrupt increase in proton con...

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Published in:Journal of the American Chemical Society 2015-05, Vol.137 (20), p.6428-6431
Main Authors: Tominaka, Satoshi, Coudert, François-Xavier, Dao, Thang D, Nagao, Tadaaki, Cheetham, Anthony K
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Material chemistry
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cited_by cdi_FETCH-LOGICAL-a499t-f0a8ba5b95649b5a0e88e0680b55c68dac1d86b815cf60a56eca4a68576604183
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container_issue 20
container_start_page 6428
container_title Journal of the American Chemical Society
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creator Tominaka, Satoshi
Coudert, François-Xavier
Dao, Thang D
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Cheetham, Anthony K
description Metal–organic frameworks (MOFs) are prone to exhibit phase transitions under stimuli such as changes in pressure, temperature, or gas sorption because of their flexible and responsive structures. Here we report that a dense MOF, ((CH3)2NH2)2­[Li2Zr­(C2O4)4], exhibits an abrupt increase in proton conductivity from
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subjects Chemical Sciences
Material chemistry
title Insulator-to-Proton-Conductor Transition in a Dense Metal–Organic Framework
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