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Influence of nanoceramic interlayer on polymer consolidation during cold-spray coating formation
[Display omitted] Nanoceramic interlayers at the polymer-polymer interfaces have been demonstrated to be extremely vital for the coating buildup (up to 4 mm thickness) during cold-spray consolidation of Ultra-High Molecular Weight Polyethylene (UHMWPE). This paper investigates the polymer-polymer in...
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Published in: | Journal of materials processing technology 2019-11, Vol.273, p.116254, Article 116254 |
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Main Authors: | , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | [Display omitted]
Nanoceramic interlayers at the polymer-polymer interfaces have been demonstrated to be extremely vital for the coating buildup (up to 4 mm thickness) during cold-spray consolidation of Ultra-High Molecular Weight Polyethylene (UHMWPE). This paper investigates the polymer-polymer interface formation and strength as a function of the compressive state of the consolidation and the influence of the interlayers at the bonding interface. The research study suggested that the polymer-polymer interfaces get reinforced at high compressive consolidation by two in-situ mechanisms: (i) formation of core-shell surface composites; (ii) formation of a network of polymer-nanoceramic-polymer knots during the polymer chain inter-diffusion. On the other hand, a low compressive consolidation fails to create the surface compositing and polymer-nanoceramic-polymer links at the polymer-polymer interface yielding a weaker interface strength compared to that of a polymer-polymer interface. The nanoceramic particles in the interlayer, in this case, acted as a defect preventing efficient wetting and subsequent inter-diffusion between adjacent polymer particles. |
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ISSN: | 0924-0136 1873-4774 |
DOI: | 10.1016/j.jmatprotec.2019.116254 |