Iron‐Catalyzed Minisci Type Acetylation of N‐Heteroarenes Mediated by CH(OEt)3/TBHP

Iron‐catalyzed acetylation of electron deficient N‐heteroarenes has been reported using triethylorthoformate as robust and inexpensive acetyl source. This new method is successfully applied for the acetylation of quinolines, isoquinoline, quinoxalines, arylpyridines, bipyridines, and benzothiazole....

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Bibliographic Details
Published in:European journal of organic chemistry 2019-02, Vol.2019 (8), p.1815-1819
Main Authors: Srinivasulu, A., Shantharjun, B., Vani, D., Ashalu, K. Chinna, Mohd, A., Wencel‐Delord, J., Colobert, F., Reddy, K. Rajender
Format: Article
Language:English
Subjects:
Acetylation
Chemical Sciences
Iron
Iron catalyst
N‐heteroarenes
Organic chemistry
Organic compounds
Quinoxalines
TBHP
Triethylorthoformate
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Summary:Iron‐catalyzed acetylation of electron deficient N‐heteroarenes has been reported using triethylorthoformate as robust and inexpensive acetyl source. This new method is successfully applied for the acetylation of quinolines, isoquinoline, quinoxalines, arylpyridines, bipyridines, and benzothiazole. Iron catalysed acetylation of electron deficient N‐heteroarenes has been reported using triethylorthoformateas robust and inexpensive acetyl source. This new method is successfully applied for the acetylation of quinolines, isoquinoline, quinoxalines, arylpyridines, bipyridines, and benzothiazole.
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.201900033