Typical features of nitrogen in nitride-type compounds

Nitride and oxynitride materials have attractive properties directly related to the role played by nitrogen. In particular, a comparison between oxynitrides and oxides highlights the characteristics of a nitrogen N3−/oxygen O2− substitution: an increase in the anionic formal charge, a greater covale...

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Published in:The international journal of inorganic materials 2001-12, Vol.3 (8), p.1143-1146
Main Authors: Marchand, Roger, Tessier, Franck, Le Sauze, André, Diot, Nadège
Format: Article
Language:English
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Chemical Sciences
Material chemistry
Nitride
Nitrogen
Oxynitride
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description Nitride and oxynitride materials have attractive properties directly related to the role played by nitrogen. In particular, a comparison between oxynitrides and oxides highlights the characteristics of a nitrogen N3−/oxygen O2− substitution: an increase in the anionic formal charge, a greater covalent character, a higher cross-linking density in glasses, a reducing character due to the N3−/N0 redox couple, and modified acid–base properties. Each specific character is illustrated by appropriate examples.
doi_str_mv 10.1016/S1466-6049(01)00145-3
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subjects Chemical Sciences
Material chemistry
Nitride
Nitrogen
Oxynitride
title Typical features of nitrogen in nitride-type compounds
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